Modification of photochemical reactivity by zeolites: Arrested molecular rotation of polyenes by inclusion in zeolites

V. Ramamurthy; J. V. Caspar; D. R. Corbin; D. F. Eaton; J. S. Kauffman; C. Dybowski

doi:10.1016/1010-6030(90)87059-K

Modification of photochemical reactivity by zeolites: Arrested molecular rotation of polyenes by inclusion in zeolites

V. Ramamurthy, J. V. Caspar, D. R. Corbin, D. F. Eaton, J. S. Kauffman, C. Dybowski

Research output: Contribution to journal › Article

32 Scopus citations

Abstract

In this work we have utilized faujasite [2] and pentasil [3] zeolites as hosts to carry out phototransformations of several organic molecules. Although they possess completely interconnecting three dimensional pore structures these two types of zeolite have fundamentally different void space topologies (Fig. 1). While the former consists of relatively large and spherical cages (diameter about 13 Å; entrance pore diameter about 8 Å), the latter contains only interconnecting channels (diameter about 5.5 Å). {A figure is presented}.

Original language	English (US)
Pages (from-to)	259-263
Number of pages	5
Journal	Journal of Photochemistry and Photobiology, A: Chemistry
Volume	51
Issue number	2
DOIs	https://doi.org/10.1016/1010-6030(90)87059-K
State	Published - Mar 1990
Externally published	Yes

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ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Physics and Astronomy(all)

Cite this

Ramamurthy, V., Caspar, J. V., Corbin, D. R., Eaton, D. F., Kauffman, J. S., & Dybowski, C. (1990). Modification of photochemical reactivity by zeolites: Arrested molecular rotation of polyenes by inclusion in zeolites. Journal of Photochemistry and Photobiology, A: Chemistry, 51(2), 259-263. https://doi.org/10.1016/1010-6030(90)87059-K

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AU - Kauffman, J. S.

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10.1016/1010-6030(90)87059-K