Modification of photochemical reactivity by zeolites: Arrested molecular rotation of polyenes by inclusion in zeolites

Vaidhyanathan Ramamurthy, J. V. Caspar, D. R. Corbin, D. F. Eaton, J. S. Kauffman, C. Dybowski

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

In this work we have utilized faujasite [2] and pentasil [3] zeolites as hosts to carry out phototransformations of several organic molecules. Although they possess completely interconnecting three dimensional pore structures these two types of zeolite have fundamentally different void space topologies (Fig. 1). While the former consists of relatively large and spherical cages (diameter about 13 Å; entrance pore diameter about 8 Å), the latter contains only interconnecting channels (diameter about 5.5 Å). {A figure is presented}.

Original languageEnglish
Pages (from-to)259-263
Number of pages5
JournalJournal of Photochemistry and Photobiology, A: Chemistry
Volume51
Issue number2
DOIs
StatePublished - Jan 1 1990
Externally publishedYes

Fingerprint

Polyenes
Zeolites
molecular rotation
Pore structure
zeolites
reactivity
Topology
inclusions
Molecules
porosity
entrances
voids
topology
molecules
faujasite

ASJC Scopus subject areas

  • Bioengineering
  • Physical and Theoretical Chemistry

Cite this

Modification of photochemical reactivity by zeolites : Arrested molecular rotation of polyenes by inclusion in zeolites. / Ramamurthy, Vaidhyanathan; Caspar, J. V.; Corbin, D. R.; Eaton, D. F.; Kauffman, J. S.; Dybowski, C.

In: Journal of Photochemistry and Photobiology, A: Chemistry, Vol. 51, No. 2, 01.01.1990, p. 259-263.

Research output: Contribution to journalArticle

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