Abstract
The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.
| Original language | English |
|---|---|
| Pages (from-to) | 3952-3956 |
| Number of pages | 5 |
| Journal | Journal of Organic Chemistry |
| Volume | 52 |
| Issue number | 18 |
| State | Published - Dec 1 1987 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Modification of photochemical reactivity by cyclodextrin. Difference in photobehavior between short chain and long chain benzoin alkyl ethers : Conformational effect. / Dasaratha Reddy, G.; Ramamurthy, Vaidhyanathan.
In: Journal of Organic Chemistry, Vol. 52, No. 18, 01.12.1987, p. 3952-3956.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Modification of photochemical reactivity by cyclodextrin. Difference in photobehavior between short chain and long chain benzoin alkyl ethers
T2 - Conformational effect
AU - Dasaratha Reddy, G.
AU - Ramamurthy, Vaidhyanathan
PY - 1987/12/1
Y1 - 1987/12/1
N2 - The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.
AB - The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.
UR - http://www.scopus.com/inward/record.url?scp=0023635058&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0023635058&partnerID=8YFLogxK
M3 - Article
VL - 52
SP - 3952
EP - 3956
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 18
ER -