Modification of Photochemical Reactivity by Cyclodextrin. Difference in Photobehavior between Short Chain and Long Chain Benzoin Alkyl Ethers: Conformational Effect

G. Dasaratha Reddy; V. Ramamurthy

doi:10.1021/jo00227a002

Modification of Photochemical Reactivity by Cyclodextrin. Difference in Photobehavior between Short Chain and Long Chain Benzoin Alkyl Ethers: Conformational Effect

G. Dasaratha Reddy, V. Ramamurthy

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.

Original language	English (US)
Pages (from-to)	3952-3956
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	52
Issue number	18
DOIs	https://doi.org/10.1021/jo00227a002
State	Published - Sep 1 1987
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Modification of Photochemical Reactivity by Cyclodextrin. Difference in Photobehavior between Short Chain and Long Chain Benzoin Alkyl Ethers: Conformational Effect",

abstract = "The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.",

author = "Reddy, {G. Dasaratha} and V. Ramamurthy",

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AU - Reddy, G. Dasaratha

AU - Ramamurthy, V.

PY - 1987/9/1

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N2 - The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.

AB - The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.

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