Modification of photochemical reactivity by cyclodextrin. Difference in photobehavior between short chain and long chain benzoin alkyl ethers

Conformational effect

G. Dasaratha Reddy, Vaidhyanathan Ramamurthy

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.

Original languageEnglish
Pages (from-to)3952-3956
Number of pages5
JournalJournal of Organic Chemistry
Volume52
Issue number18
StatePublished - Dec 1 1987
Externally publishedYes

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Benzoin
Ethers
Cyclodextrins
Photolysis

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

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abstract = "The photochemical behavior of long chain benzoin alkyl ethers when complexed to β-cyclodextrin has been investigated with the view to understand their chemical behavior when included in the above host matrix. Photolysis results in benzil and pinacol ethers as the main products in solid β-cyclodextrin complex and benzaldehyde, benzil, pinacol ethers, and deoxybenzoin in aqueous β-cyclodextrin complex. The results on long chain benzoin alkyl ethers 4-6 are distinctly different from those of short chain benzoin alkyl ethers 1-3.",
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