Mediated electrochemical oxidation of a fully encapsulated redox active center

Dagmara Podkoscielny; Suresh Gadde; Angel E. Kaifer

doi:10.1021/ja9045108

Mediated electrochemical oxidation of a fully encapsulated redox active center

Dagmara Podkoscielny, Suresh Gadde, Angel E. Kaifer

Chemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

(Figure Presented) While the direct electrochemical oxidation of ferrocene encapsulated inside a dimeric molecular capsule is essentially suppressed, a cationic ferrocene derivative binds to the capsule's external surface and acts as an effective electrochemical mediator.

Original language	English (US)
Pages (from-to)	12876-12877
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	36
DOIs	https://doi.org/10.1021/ja9045108
State	Published - Sep 16 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "Mediated electrochemical oxidation of a fully encapsulated redox active center",

abstract = "(Figure Presented) While the direct electrochemical oxidation of ferrocene encapsulated inside a dimeric molecular capsule is essentially suppressed, a cationic ferrocene derivative binds to the capsule's external surface and acts as an effective electrochemical mediator.",

author = "Dagmara Podkoscielny and Suresh Gadde and Kaifer, {Angel E.}",

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AU - Gadde, Suresh

AU - Kaifer, Angel E.

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N2 - (Figure Presented) While the direct electrochemical oxidation of ferrocene encapsulated inside a dimeric molecular capsule is essentially suppressed, a cationic ferrocene derivative binds to the capsule's external surface and acts as an effective electrochemical mediator.

AB - (Figure Presented) While the direct electrochemical oxidation of ferrocene encapsulated inside a dimeric molecular capsule is essentially suppressed, a cationic ferrocene derivative binds to the capsule's external surface and acts as an effective electrochemical mediator.

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JF - Journal of the American Chemical Society

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Mediated electrochemical oxidation of a fully encapsulated redox active center

Abstract

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