Mechanisms of reverse current and mitigation strategies in proton exchange membrane fuel cells during startups

Fei Jia, Fengfeng Liu, Liejin Guo, Hongtan Liu

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Understanding the dynamic behaviors of proton exchange membrane (PEM) fuel cells during startups is crucial for their proper operations to minimizing the detrimental effects of reverse current. In this study, the fuel cell is initially filled with nitrogen at both sides, and then reactants are supplied to the cell and the load is imposed simultaneously. Experimental results show that reverse current still occurs even though nitrogen purging is employed before the startup and hydrogen/air boundary is eliminated at the anode. The magnitude of reverse current density increases with the startup voltage. Analysis shows that the reverse current is proportional to the difference between the startup voltage and the open circuit voltage, and it occurs only when the open circuit voltage is lower than the startup voltage, which is due to the charging of the electrical double-layer on the cathode. Thus a startup strategy of air pre-filling is devised and the experimental results show that reverse current can be completely avoided or significantly reduced by pre-filling the cathode with air before startups. Another startup strategy, a linear startup mode, is also tested and the results show that it is effective in reducing the reverse current.

Original languageEnglish (US)
Pages (from-to)6469-6475
Number of pages7
JournalInternational Journal of Hydrogen Energy
Volume41
Issue number15
DOIs
StatePublished - Apr 27 2016

Fingerprint

Proton exchange membrane fuel cells (PEMFC)
fuel cells
Open circuit voltage
membranes
protons
Electric potential
Cathodes
Air
Nitrogen
Purging
open circuit voltage
air
electric potential
cathodes
Fuel cells
Anodes
purging
Current density
nitrogen
Hydrogen

Keywords

  • Proton exchange membrane fuel cell (PEMFC)
  • Reverse current density
  • Startup strategy
  • Startups

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Mechanisms of reverse current and mitigation strategies in proton exchange membrane fuel cells during startups. / Jia, Fei; Liu, Fengfeng; Guo, Liejin; Liu, Hongtan.

In: International Journal of Hydrogen Energy, Vol. 41, No. 15, 27.04.2016, p. 6469-6475.

Research output: Contribution to journalArticle

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