Measuring chirality in NMR in the presence of a static electric field

Jamie D. Walls; Robert A. Harris; Cynthia J. Jameson

doi:10.1063/1.2888555

Measuring chirality in NMR in the presence of a static electric field

Jamie D. Walls, Robert A. Harris, Cynthia J. Jameson

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The scalar Hamiltonian of nuclear spins in the presence of a static electric field supports chirality. However, the eigenvalues of the Hamiltonian are not chiral; hence, chirality is not manifested in the usual NMR experiment. In this work, we show that the magnetization response to certain radio frequency pulse sequences exhibits chirality as well as handedness.

Original language	English (US)
Article number	154502
Journal	Journal of Chemical Physics
Volume	128
Issue number	15
DOIs	https://doi.org/10.1063/1.2888555
State	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Measuring chirality in NMR in the presence of a static electric field",

abstract = "The scalar Hamiltonian of nuclear spins in the presence of a static electric field supports chirality. However, the eigenvalues of the Hamiltonian are not chiral; hence, chirality is not manifested in the usual NMR experiment. In this work, we show that the magnetization response to certain radio frequency pulse sequences exhibits chirality as well as handedness.",

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AB - The scalar Hamiltonian of nuclear spins in the presence of a static electric field supports chirality. However, the eigenvalues of the Hamiltonian are not chiral; hence, chirality is not manifested in the usual NMR experiment. In this work, we show that the magnetization response to certain radio frequency pulse sequences exhibits chirality as well as handedness.

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

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Measuring chirality in NMR in the presence of a static electric field

Abstract

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