Abstract
The scalar Hamiltonian of nuclear spins in the presence of a static electric field supports chirality. However, the eigenvalues of the Hamiltonian are not chiral; hence, chirality is not manifested in the usual NMR experiment. In this work, we show that the magnetization response to certain radio frequency pulse sequences exhibits chirality as well as handedness.
| Original language | English (US) |
|---|---|
| Article number | 154502 |
| Journal | Journal of Chemical Physics |
| Volume | 128 |
| Issue number | 15 |
| DOIs | |
| State | Published - Apr 28 2008 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Cite this
Walls, J. D., Harris, R. A., & Jameson, C. J. (2008). Measuring chirality in NMR in the presence of a static electric field. Journal of Chemical Physics, 128(15), [154502]. https://doi.org/10.1063/1.2888555