Abstract
Simulations of reversible polycondensations with chain-length dependent reactivity of functional groups are carried out for three idealized reactor-geometries usually encountered in industry. It is observed that the molecular-weight-distributions (MWDs) depend on the location in the reaction mass when the equilibrium is unfavourable to the formation of high molecular-weight polymer. The MWDs split into two curves - for odd and even values of n, under certain conditions. However, it is confirmed that a representation of the MWDs in terms of a single parameter p, the conversion of functional groups, is not possible for unequal-reactivity polycondensations.
| Original language | English (US) |
|---|---|
| Publisher | John Wiley & Sons |
| Number of pages | 17 |
| State | Published - 1984 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Engineering(all)
Cite this
MASS TRANSFER WITH REVERSIBLE POLYCONDENSATION REACTIONS WHEREIN FUNCTIONAL GROUPS ARE NOT EQUALLY REACTIVE. / Gupta, Santosh K.; Rao, Singiresu S; Agarwal, R.; Anil Kumar, Kumar.
John Wiley & Sons, 1984. 17 p.Research output: Book/Report › Book
}
TY - BOOK
T1 - MASS TRANSFER WITH REVERSIBLE POLYCONDENSATION REACTIONS WHEREIN FUNCTIONAL GROUPS ARE NOT EQUALLY REACTIVE.
AU - Gupta, Santosh K.
AU - Rao, Singiresu S
AU - Agarwal, R.
AU - Anil Kumar, Kumar
PY - 1984
Y1 - 1984
N2 - Simulations of reversible polycondensations with chain-length dependent reactivity of functional groups are carried out for three idealized reactor-geometries usually encountered in industry. It is observed that the molecular-weight-distributions (MWDs) depend on the location in the reaction mass when the equilibrium is unfavourable to the formation of high molecular-weight polymer. The MWDs split into two curves - for odd and even values of n, under certain conditions. However, it is confirmed that a representation of the MWDs in terms of a single parameter p, the conversion of functional groups, is not possible for unequal-reactivity polycondensations.
AB - Simulations of reversible polycondensations with chain-length dependent reactivity of functional groups are carried out for three idealized reactor-geometries usually encountered in industry. It is observed that the molecular-weight-distributions (MWDs) depend on the location in the reaction mass when the equilibrium is unfavourable to the formation of high molecular-weight polymer. The MWDs split into two curves - for odd and even values of n, under certain conditions. However, it is confirmed that a representation of the MWDs in terms of a single parameter p, the conversion of functional groups, is not possible for unequal-reactivity polycondensations.
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UR - http://www.scopus.com/inward/citedby.url?scp=0021691982&partnerID=8YFLogxK
M3 - Book
AN - SCOPUS:0021691982
BT - MASS TRANSFER WITH REVERSIBLE POLYCONDENSATION REACTIONS WHEREIN FUNCTIONAL GROUPS ARE NOT EQUALLY REACTIVE.
PB - John Wiley & Sons
ER -