Local lattice distortions and thermal transport in perovskite manganites

Measurements of thermal conductivity versus temperature and magnetic field are reported for perovskite manganites that exhibit ferromagnetic (FM), charge-ordering (CO), antiferromagnetic, and/or structural phase transitions. The data reveal a dominant lattice contribution to the heat conductivity with (Formula presented) W/mK near room temperature. The rather low values, implying a phonon mean free path on the order of a lattice spacing, are shown to correlate with static local distortions of the (Formula presented) octahedra. Modifications of the local structure are responsible for abrupt anomalies in the zero-field κ at the FM, CO, and structural transitions, and for colossal magnetothermal resistance near the FM transition.