Linker-free quantum dot sensitized TiO2 photoelectrochemical cells

Liying Zhu, Woo Jin An, Joseph W. Springer, Luis B. Modesto-Lopez, Sravani Gullapalli, Dewey Holten, Michael S. Wong, Pratim Biswas

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Aerosol based techniques were used to characterize and deposit quantum dots (QDs). Using an electrospray-assisted characterization technique, the mobility diameter of CdSe QDs was successfully measured in real-time. The electrospray technique was also used to deposit CdSe QDs onto nanostructured TiO2 films. Compared to conventional methodologies such as dip coating with linker-containing molecules or chemical bath deposition, an electrospray system enabled uniform deposition of QDs over the nanostructured TiO2 surface in a short processing time. As-deposited films were annealed to enhance binding between the QDs and TiO2 surface. These QD-decorated TiO 2 films were used in photoelectrochemical cells, for which the photoenergy conversion efficiencies were tested. Optimization of the deposition time of the QDs resulted in increased efficiencies. Multiple layers of QDs caused a decrease in energy-conversion efficiency, likely due to inhibition of the transportation of photogenerated electrons into the TiO2 structure. The energy-conversion efficiency trends were supported by time-resolved photoluminescence decay data.

Original languageEnglish (US)
Pages (from-to)6422-6430
Number of pages9
JournalInternational Journal of Hydrogen Energy
Volume37
Issue number8
DOIs
StatePublished - Apr 2012
Externally publishedYes

Keywords

  • Electrospray
  • Oxide semiconductors
  • Quantum dots
  • Solar hydrogen
  • Water splitting

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

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