Abstract
A series of new palladium-ruthenium cluster complexes have been prepared by adding Pd(PBut3) fragments to the ruthenium-ruthenium bonds of ruthenium carbonyl complexes. Reaction of Pd(PBut3)2 with Ru3(CO)12yielded the tripalladium adduct Ru3(CO)12[Pd(PBut3)]3 1. Compound 1 contains three Pd(PBut3) groups symmetrically disposed with each one acting as a bridge across one Ru-Ru bond of the former Ru3(CO)12 molecule. Reaction of Pd(PBut3)2 with Ru6(CO)17(C) yielded the dipalladium adduct Ru6(CO)17(C)[Pd(PBut3)]2 2. Compound 2 exists as two isomers in the solid state. One isomer has Pd(PBut3) groups bridging two edges of the Ru6 octahedron. The other isomer has a Pd(PBut3) group bridging one edge of the Ru6 octahedron, and the other is a triple bridge. The reaction of Pd(PBut3)2 with Ru(CO)5 yielded the dipalladium-diruthenium complex Ru2(CO)9[Pd(PBut3)]2 3, a dipalladium adduct of the unstable molecule Ru2(CO)9.
| Original language | English |
|---|---|
| Pages (from-to) | 5628-5629 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 124 |
| Issue number | 20 |
| DOIs | |
| State | Published - May 22 2002 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry(all)
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Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes. / Adams, Richard D.; Captain, Burjor; Fu, Wei; Smith, Mark D.
In: Journal of the American Chemical Society, Vol. 124, No. 20, 22.05.2002, p. 5628-5629.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes
AU - Adams, Richard D.
AU - Captain, Burjor
AU - Fu, Wei
AU - Smith, Mark D.
PY - 2002/5/22
Y1 - 2002/5/22
N2 - A series of new palladium-ruthenium cluster complexes have been prepared by adding Pd(PBut3) fragments to the ruthenium-ruthenium bonds of ruthenium carbonyl complexes. Reaction of Pd(PBut3)2 with Ru3(CO)12yielded the tripalladium adduct Ru3(CO)12[Pd(PBut3)]3 1. Compound 1 contains three Pd(PBut3) groups symmetrically disposed with each one acting as a bridge across one Ru-Ru bond of the former Ru3(CO)12 molecule. Reaction of Pd(PBut3)2 with Ru6(CO)17(C) yielded the dipalladium adduct Ru6(CO)17(C)[Pd(PBut3)]2 2. Compound 2 exists as two isomers in the solid state. One isomer has Pd(PBut3) groups bridging two edges of the Ru6 octahedron. The other isomer has a Pd(PBut3) group bridging one edge of the Ru6 octahedron, and the other is a triple bridge. The reaction of Pd(PBut3)2 with Ru(CO)5 yielded the dipalladium-diruthenium complex Ru2(CO)9[Pd(PBut3)]2 3, a dipalladium adduct of the unstable molecule Ru2(CO)9.
AB - A series of new palladium-ruthenium cluster complexes have been prepared by adding Pd(PBut3) fragments to the ruthenium-ruthenium bonds of ruthenium carbonyl complexes. Reaction of Pd(PBut3)2 with Ru3(CO)12yielded the tripalladium adduct Ru3(CO)12[Pd(PBut3)]3 1. Compound 1 contains three Pd(PBut3) groups symmetrically disposed with each one acting as a bridge across one Ru-Ru bond of the former Ru3(CO)12 molecule. Reaction of Pd(PBut3)2 with Ru6(CO)17(C) yielded the dipalladium adduct Ru6(CO)17(C)[Pd(PBut3)]2 2. Compound 2 exists as two isomers in the solid state. One isomer has Pd(PBut3) groups bridging two edges of the Ru6 octahedron. The other isomer has a Pd(PBut3) group bridging one edge of the Ru6 octahedron, and the other is a triple bridge. The reaction of Pd(PBut3)2 with Ru(CO)5 yielded the dipalladium-diruthenium complex Ru2(CO)9[Pd(PBut3)]2 3, a dipalladium adduct of the unstable molecule Ru2(CO)9.
UR - http://www.scopus.com/inward/record.url?scp=0037157165&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037157165&partnerID=8YFLogxK
U2 - 10.1021/ja017486j
DO - 10.1021/ja017486j
M3 - Article
C2 - 12010022
AN - SCOPUS:0037157165
VL - 124
SP - 5628
EP - 5629
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 20
ER -