Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes

Richard D. Adams; Burjor Captain; Wei Fu; Mark D. Smith

doi:10.1021/ja017486j

Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes

Richard D. Adams, Burjor Captain, Wei Fu, Mark D. Smith

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

A series of new palladium-ruthenium cluster complexes have been prepared by adding Pd(PBu^t₃) fragments to the ruthenium-ruthenium bonds of ruthenium carbonyl complexes. Reaction of Pd(PBu^t₃)₂ with Ru₃(CO)₁₂yielded the tripalladium adduct Ru₃(CO)₁₂[Pd(PBu^t₃)]₃ 1. Compound 1 contains three Pd(PBu^t₃) groups symmetrically disposed with each one acting as a bridge across one Ru-Ru bond of the former Ru₃(CO)₁₂ molecule. Reaction of Pd(PBu^t₃)₂ with Ru₆(CO)₁₇(C) yielded the dipalladium adduct Ru₆(CO)₁₇(C)[Pd(PBu^t₃)]₂ 2. Compound 2 exists as two isomers in the solid state. One isomer has Pd(PBu^t₃) groups bridging two edges of the Ru₆ octahedron. The other isomer has a Pd(PBu^t₃) group bridging one edge of the Ru₆ octahedron, and the other is a triple bridge. The reaction of Pd(PBu^t₃)₂ with Ru(CO)₅ yielded the dipalladium-diruthenium complex Ru₂(CO)₉[Pd(PBu^t₃)]₂ 3, a dipalladium adduct of the unstable molecule Ru₂(CO)₉.

Original language	English (US)
Pages (from-to)	5628-5629
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	20
DOIs	https://doi.org/10.1021/ja017486j
State	Published - May 22 2002
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja017486j

Fingerprint Dive into the research topics of 'Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes'. Together they form a unique fingerprint.

Cite this

@article{cb4839ead09f40e88cea95fb095cff8d,

title = "Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes",

abstract = "A series of new palladium-ruthenium cluster complexes have been prepared by adding Pd(PBut3) fragments to the ruthenium-ruthenium bonds of ruthenium carbonyl complexes. Reaction of Pd(PBut3)2 with Ru3(CO)12yielded the tripalladium adduct Ru3(CO)12[Pd(PBut3)]3 1. Compound 1 contains three Pd(PBut3) groups symmetrically disposed with each one acting as a bridge across one Ru-Ru bond of the former Ru3(CO)12 molecule. Reaction of Pd(PBut3)2 with Ru6(CO)17(C) yielded the dipalladium adduct Ru6(CO)17(C)[Pd(PBut3)]2 2. Compound 2 exists as two isomers in the solid state. One isomer has Pd(PBut3) groups bridging two edges of the Ru6 octahedron. The other isomer has a Pd(PBut3) group bridging one edge of the Ru6 octahedron, and the other is a triple bridge. The reaction of Pd(PBut3)2 with Ru(CO)5 yielded the dipalladium-diruthenium complex Ru2(CO)9[Pd(PBut3)]2 3, a dipalladium adduct of the unstable molecule Ru2(CO)9.",

author = "Adams, {Richard D.} and Burjor Captain and Wei Fu and Smith, {Mark D.}",

year = "2002",

month = may,

day = "22",

doi = "10.1021/ja017486j",

language = "English (US)",

volume = "124",

pages = "5628--5629",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes

AU - Adams, Richard D.

AU - Captain, Burjor

AU - Fu, Wei

AU - Smith, Mark D.

PY - 2002/5/22

Y1 - 2002/5/22

N2 - A series of new palladium-ruthenium cluster complexes have been prepared by adding Pd(PBut3) fragments to the ruthenium-ruthenium bonds of ruthenium carbonyl complexes. Reaction of Pd(PBut3)2 with Ru3(CO)12yielded the tripalladium adduct Ru3(CO)12[Pd(PBut3)]3 1. Compound 1 contains three Pd(PBut3) groups symmetrically disposed with each one acting as a bridge across one Ru-Ru bond of the former Ru3(CO)12 molecule. Reaction of Pd(PBut3)2 with Ru6(CO)17(C) yielded the dipalladium adduct Ru6(CO)17(C)[Pd(PBut3)]2 2. Compound 2 exists as two isomers in the solid state. One isomer has Pd(PBut3) groups bridging two edges of the Ru6 octahedron. The other isomer has a Pd(PBut3) group bridging one edge of the Ru6 octahedron, and the other is a triple bridge. The reaction of Pd(PBut3)2 with Ru(CO)5 yielded the dipalladium-diruthenium complex Ru2(CO)9[Pd(PBut3)]2 3, a dipalladium adduct of the unstable molecule Ru2(CO)9.

AB - A series of new palladium-ruthenium cluster complexes have been prepared by adding Pd(PBut3) fragments to the ruthenium-ruthenium bonds of ruthenium carbonyl complexes. Reaction of Pd(PBut3)2 with Ru3(CO)12yielded the tripalladium adduct Ru3(CO)12[Pd(PBut3)]3 1. Compound 1 contains three Pd(PBut3) groups symmetrically disposed with each one acting as a bridge across one Ru-Ru bond of the former Ru3(CO)12 molecule. Reaction of Pd(PBut3)2 with Ru6(CO)17(C) yielded the dipalladium adduct Ru6(CO)17(C)[Pd(PBut3)]2 2. Compound 2 exists as two isomers in the solid state. One isomer has Pd(PBut3) groups bridging two edges of the Ru6 octahedron. The other isomer has a Pd(PBut3) group bridging one edge of the Ru6 octahedron, and the other is a triple bridge. The reaction of Pd(PBut3)2 with Ru(CO)5 yielded the dipalladium-diruthenium complex Ru2(CO)9[Pd(PBut3)]2 3, a dipalladium adduct of the unstable molecule Ru2(CO)9.

UR - http://www.scopus.com/inward/record.url?scp=0037157165&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037157165&partnerID=8YFLogxK

U2 - 10.1021/ja017486j

DO - 10.1021/ja017486j

M3 - Article

C2 - 12010022

AN - SCOPUS:0037157165

VL - 124

SP - 5628

EP - 5629

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 20

ER -

Lewis acid-base interactions between metal atoms and their applications for the synthesis of bimetallic cluster complexes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this