Laser-induced fluorescence study of radiative lifetimes and quenching rates in CS A1Π(υ = 0)

Anthony J. Hynes, John H. Brophy

Research output: Contribution to journalArticle

20 Scopus citations

Abstract

Radiative lifetimes and quenching rates have been measured for rotational levels of CS A 1Π(υ = 0) throughout the region of perturbation by the a′3 Σ(υ = 10) state. The measured lifetimes reflect the extent of mixing with the a′3Σ state and from the unperturbed value of τ = 171 ± 10 ns the oscillator strenght and transition moment of the CS A 1Π-X 1Σ(0,0) band are calculated to be f00 = 1.0(±0.1) × 10-2 and Re (r00) = 0.32 ± 0.09 au, respectively.

Original languageEnglish (US)
Pages (from-to)93-96
Number of pages4
JournalChemical Physics Letters
Volume63
Issue number1
DOIs
StatePublished - May 1 1979
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Laser-induced fluorescence study of radiative lifetimes and quenching rates in CS A<sup>1</sup>Π(υ = 0)'. Together they form a unique fingerprint.

  • Cite this