Large molecular motions are tolerated in crystals of diamine double salt of trans-chlorocinnamic acids with trans-1,2-diaminocyclohexane

Arunkumar Natarajan, Joel T. Mague, K. Venkatesan, Vaidhyanathan Ramamurthy

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

(Chemical Equation Presented) Contrary to the general assumption that photoreactions in crystals may not proceed with large molecular motions, a pedal-like motion prompted by electronic excitation is believed to be involved during the β-dimer formation from the crystals of the diamine double salt of trans-2,4-dichlorocinnamic acid and trans-1,2-diaminocyclohexane.

Original languageEnglish
Pages (from-to)1895-1898
Number of pages4
JournalOrganic Letters
Volume7
Issue number10
DOIs
StatePublished - May 12 2005

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Diamines
diamines
pedals
Salts
salts
Crystals
acids
Acids
Dimers
crystals
Foot
dimers
electronics
excitation
1,2-cyclohexanediamine
2,4-dichlorocinnamic acid

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Large molecular motions are tolerated in crystals of diamine double salt of trans-chlorocinnamic acids with trans-1,2-diaminocyclohexane. / Natarajan, Arunkumar; Mague, Joel T.; Venkatesan, K.; Ramamurthy, Vaidhyanathan.

In: Organic Letters, Vol. 7, No. 10, 12.05.2005, p. 1895-1898.

Research output: Contribution to journalArticle

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