Abstract
While there is evidence for the existence of HCo(CO)//3,**6 there is no information regarding the rate of formation of this compound or analogous alkyl and acylcobalt tricarbonyls. The author also report measurements of the rates of **1**3CO exchange for each of these species. These data provide support for the authors proposed mechanism and furnish fundamental information relevant to the hydroformylation reaction.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 666-671 |
| Number of pages | 6 |
| Journal | Journal of the American Chemical Society |
| Volume | 107 |
| Issue number | 3 |
| DOIs | |
| State | Published - Feb 1985 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Hoff, C. D., Ungvary, F., Marko, L., & King, R. B. (1985). Kinetics of the Reactions of (Ethoxycarbonyl)methylcobalt Tetracarbonyl with 13CO, Ph3P, Hco(co)4, and H2. A Comparison of the Reactivities of Rco(co)4(R = CH2COOEt, COOEt, and H) Complexes. Journal of the American Chemical Society, 107(3), 666-671. https://doi.org/10.1021/ja00289a019