Kinetics of the Reactions of (Ethoxycarbonyl)methylcobalt Tetracarbonyl with 13CO, Ph3P, Hco(co)4, and H2. A Comparison of the Reactivities of Rco(co)4(R = CH2COOEt, COOEt, and H) Complexes

C. D. Hoff, F. Ungvary, L. Marko, R. B. King

Research output: Contribution to journalArticle

47 Scopus citations

Abstract

While there is evidence for the existence of HCo(CO)//3,**6 there is no information regarding the rate of formation of this compound or analogous alkyl and acylcobalt tricarbonyls. The author also report measurements of the rates of **1**3CO exchange for each of these species. These data provide support for the authors proposed mechanism and furnish fundamental information relevant to the hydroformylation reaction.

Original languageEnglish (US)
Pages (from-to)666-671
Number of pages6
JournalJournal of the American Chemical Society
Volume107
Issue number3
DOIs
StatePublished - Feb 1985

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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