Isotropic proton-detected local-field nuclear magnetic resonance in solids

Robert H. Havlin; Jamie D. Walls; Alexander Pines

doi:10.1063/1.1844296

Isotropic proton-detected local-field nuclear magnetic resonance in solids

Robert H. Havlin, Jamie D. Walls, Alexander Pines

Research output: Contribution to journal › Article

1 Scopus citations

Abstract

A nuclear magnetic resonance method is presented which produces linear, isotropic proton-detected local-field spectra for I _NS spin systems in powdered samples. The method, heteronuclear isotropic evolution (HETIE), refocuses the anisotropic portion of the heteronuclear dipolar coupling frequencies by evolving the system under a series of specially designed Hamiltonians and evolution pathways. The theory behind HETIE is presented along with experimental studies conducted on a powdered sample of ferrocene, demonstrating the methodology outlined in this paper. Applications of HETIE for use in structure determination in the solid state are discussed.

Original language	English (US)
Article number	074507
Journal	Journal of Chemical Physics
Volume	122
Issue number	7
DOIs	https://doi.org/10.1063/1.1844296
State	Published - Aug 5 2005
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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Havlin, R. H., Walls, J. D., & Pines, A. (2005). Isotropic proton-detected local-field nuclear magnetic resonance in solids. Journal of Chemical Physics, 122(7), [074507]. https://doi.org/10.1063/1.1844296

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