Intramolecular nitroalkene diels-alder reaction catalyzed by brønsted acids

Andreina Aguado, Norito Takenaka

Research output: Contribution to journalArticle

12 Scopus citations

Abstract

Brønsted acid catalysis of intramolecular Diels-Alder cyclizations of (E)-1-nitro-1,6,8-nonatrienes and (E)-1-nitro-1,7,9-decatrienes was investigated. Catalyzed reactions showed significantly higher endo selectivities than the corresponding thermal reactions. To our knowledge, this is the first example of catalysis (substoichiometric amount of catalysts) of the intramolecular nitroalkene Diels-Alder reaction.

Original languageEnglish (US)
Article numberY03311ST
Pages (from-to)1259-1261
Number of pages3
JournalSynlett
Issue number9
DOIs
StatePublished - May 30 2011

Keywords

  • Brønsted acid catalysis
  • catalysis
  • intramolecular Diels-Alder cyclizations

ASJC Scopus subject areas

  • Organic Chemistry

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