Intramolecular nitroalkene diels-alder reaction catalyzed by brønsted acids

Andreina Aguado, Norito Takenaka

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Brønsted acid catalysis of intramolecular Diels-Alder cyclizations of (E)-1-nitro-1,6,8-nonatrienes and (E)-1-nitro-1,7,9-decatrienes was investigated. Catalyzed reactions showed significantly higher endo selectivities than the corresponding thermal reactions. To our knowledge, this is the first example of catalysis (substoichiometric amount of catalysts) of the intramolecular nitroalkene Diels-Alder reaction.

Original languageEnglish (US)
Article numberY03311ST
Pages (from-to)1259-1261
Number of pages3
JournalSynlett
Issue number9
DOIs
StatePublished - 2011
Externally publishedYes

Fingerprint

Catalysis
Acids
Cyclization
Catalysts
Hot Temperature

Keywords

  • Brønsted acid catalysis
  • catalysis
  • intramolecular Diels-Alder cyclizations

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Intramolecular nitroalkene diels-alder reaction catalyzed by brønsted acids. / Aguado, Andreina; Takenaka, Norito.

In: Synlett, No. 9, Y03311ST, 2011, p. 1259-1261.

Research output: Contribution to journalArticle

Aguado, Andreina ; Takenaka, Norito. / Intramolecular nitroalkene diels-alder reaction catalyzed by brønsted acids. In: Synlett. 2011 ; No. 9. pp. 1259-1261.
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