Insulator-to-metal transition in polyaniline

A. J. Epstein, J. M. Ginder, F. Zuo, R. W. Bigelow, H. S. Woo, D. B. Tanner, A. F. Richter, W. S. Huang, A. G. MacDiarmid

Research output: Contribution to journalArticlepeer-review

553 Scopus citations

Abstract

The emeraldine base (EB) form of polyaniline can be varied from insulating (σ < 10-10ohm-1cm-1) to conducting (σ ≈ 10+1ohm-cm-) through protonation. That is, the number of electrons on the polymer backbone is constant while the number of protons is increased. We present here extensive magnetic, optical and transport data that demonstrate that the resulting emeraldine salt (ES) is metallic with a finite density of states at the Fermi energy. The results are consistent with segregation into fully protonated emeraldine salt and unprotonated emeraldine base polymer regions. it is proposed that the observed transition is an isolated bipolaron-to-polaron lattice transition. The correspondence of this concept to the disproportionation between protonated imine plus amine to form two semiquinones is shown.

Original languageEnglish (US)
Pages (from-to)303-309
Number of pages7
JournalSynthetic Metals
Volume18
Issue number1-3
DOIs
StatePublished - Feb 1987
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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