Inclusion of anthraquinone derivatives by the cucurbit[7]uril host

Vladimir Sindelar; Samantha E. Parker; Angel E. Kaifer

doi:10.1039/b615803j

Inclusion of anthraquinone derivatives by the cucurbit[7]uril host

Vladimir Sindelar, Samantha E. Parker, Angel E. Kaifer

Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Two simple cationic anthraquinone derivatives were found to form stable complexes with the cucurbit[7]uril host, in which the anthraquinone residue is included by the host cavity. The corresponding equilibrium association constants were relatively low (K ∼10³ M^-1) - compared to those of other complexes formed by the same host - suggesting that anthraquinone is not an ideal guest. However, the electrochemical behavior of the guests is strongly affected by inclusion inside the host cavity.

Original language	English (US)
Pages (from-to)	725-728
Number of pages	4
Journal	New Journal of Chemistry
Volume	31
Issue number	5
DOIs	https://doi.org/10.1039/b615803j
State	Published - Jan 1 2007

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Materials Chemistry

Access to Document

10.1039/b615803j

Cite this

@article{9bcd46ec80c047c881148dafc0e41605,

title = "Inclusion of anthraquinone derivatives by the cucurbit[7]uril host",

abstract = "Two simple cationic anthraquinone derivatives were found to form stable complexes with the cucurbit[7]uril host, in which the anthraquinone residue is included by the host cavity. The corresponding equilibrium association constants were relatively low (K ∼103 M-1) - compared to those of other complexes formed by the same host - suggesting that anthraquinone is not an ideal guest. However, the electrochemical behavior of the guests is strongly affected by inclusion inside the host cavity.",

author = "Vladimir Sindelar and Parker, {Samantha E.} and Kaifer, {Angel E.}",

year = "2007",

month = jan,

day = "1",

doi = "10.1039/b615803j",

language = "English (US)",

volume = "31",

pages = "725--728",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Inclusion of anthraquinone derivatives by the cucurbit[7]uril host

AU - Sindelar, Vladimir

AU - Parker, Samantha E.

AU - Kaifer, Angel E.

PY - 2007/1/1

Y1 - 2007/1/1

N2 - Two simple cationic anthraquinone derivatives were found to form stable complexes with the cucurbit[7]uril host, in which the anthraquinone residue is included by the host cavity. The corresponding equilibrium association constants were relatively low (K ∼103 M-1) - compared to those of other complexes formed by the same host - suggesting that anthraquinone is not an ideal guest. However, the electrochemical behavior of the guests is strongly affected by inclusion inside the host cavity.

AB - Two simple cationic anthraquinone derivatives were found to form stable complexes with the cucurbit[7]uril host, in which the anthraquinone residue is included by the host cavity. The corresponding equilibrium association constants were relatively low (K ∼103 M-1) - compared to those of other complexes formed by the same host - suggesting that anthraquinone is not an ideal guest. However, the electrochemical behavior of the guests is strongly affected by inclusion inside the host cavity.

UR - http://www.scopus.com/inward/record.url?scp=34248389666&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34248389666&partnerID=8YFLogxK

U2 - 10.1039/b615803j

DO - 10.1039/b615803j

M3 - Article

AN - SCOPUS:34248389666

VL - 31

SP - 725

EP - 728

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 5

ER -

Inclusion of anthraquinone derivatives by the cucurbit[7]uril host

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this