Hydrogen bonding in macrocyclic receptor systems

Bert C. Lynn; Mara Tsfsarskaja; Otto Schall; Jeanette C. Hernandez; Shigeru Watanabe; Angel Kaifer; Toshio Takailashi; George W. Gokel

doi:10.1080/10610279308035168

Hydrogen bonding in macrocyclic receptor systems

Bert C. Lynn, Mara Tsfsarskaja, Otto Schall, Jeanette C. Hernandez, Shigeru Watanabe, Angel Kaifer, Toshio Takailashi, George W. Gokel

Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The interactions of macrocyclic polyethers with alkali and alkaline earth cations have been well studied and much about their chemistry is now well understood. Less well examined or comprehended are hydrogen bond interactions. A combination of ion selective electrode binding constant determination techniques and fast atom bombardment mass spectrometry are brought to bear on this problem. It is found that all-oxygen crown ethers and their derivatives exhibit quite different complexation behaviour with ammonium salts than do their various azacrown counterparts.

Original language	English (US)
Pages (from-to)	253-260
Number of pages	8
Journal	Supramolecular Chemistry
Volume	1
Issue number	3-4
DOIs	https://doi.org/10.1080/10610279308035168
State	Published - 1993

ASJC Scopus subject areas

Chemistry(all)

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title = "Hydrogen bonding in macrocyclic receptor systems",

abstract = "The interactions of macrocyclic polyethers with alkali and alkaline earth cations have been well studied and much about their chemistry is now well understood. Less well examined or comprehended are hydrogen bond interactions. A combination of ion selective electrode binding constant determination techniques and fast atom bombardment mass spectrometry are brought to bear on this problem. It is found that all-oxygen crown ethers and their derivatives exhibit quite different complexation behaviour with ammonium salts than do their various azacrown counterparts.",

author = "Lynn, {Bert C.} and Mara Tsfsarskaja and Otto Schall and Hernandez, {Jeanette C.} and Shigeru Watanabe and Angel Kaifer and Toshio Takailashi and Gokel, {George W.}",

note = "Funding Information: We thank the NIH for a grant (GM 36262) that supported this work.",

year = "1993",

doi = "10.1080/10610279308035168",

language = "English (US)",

volume = "1",

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journal = "Supramolecular Chemistry",

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T1 - Hydrogen bonding in macrocyclic receptor systems

AU - Lynn, Bert C.

AU - Tsfsarskaja, Mara

AU - Schall, Otto

AU - Hernandez, Jeanette C.

AU - Watanabe, Shigeru

AU - Kaifer, Angel

AU - Takailashi, Toshio

AU - Gokel, George W.

N1 - Funding Information: We thank the NIH for a grant (GM 36262) that supported this work.

PY - 1993

Y1 - 1993

N2 - The interactions of macrocyclic polyethers with alkali and alkaline earth cations have been well studied and much about their chemistry is now well understood. Less well examined or comprehended are hydrogen bond interactions. A combination of ion selective electrode binding constant determination techniques and fast atom bombardment mass spectrometry are brought to bear on this problem. It is found that all-oxygen crown ethers and their derivatives exhibit quite different complexation behaviour with ammonium salts than do their various azacrown counterparts.

AB - The interactions of macrocyclic polyethers with alkali and alkaline earth cations have been well studied and much about their chemistry is now well understood. Less well examined or comprehended are hydrogen bond interactions. A combination of ion selective electrode binding constant determination techniques and fast atom bombardment mass spectrometry are brought to bear on this problem. It is found that all-oxygen crown ethers and their derivatives exhibit quite different complexation behaviour with ammonium salts than do their various azacrown counterparts.

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