Generation and reactivity of singlet oxygen within zeolites: Remarkable control of hydroperoxidation of alkenes

Rebecca J. Robbins; V. Ramamurthy

doi:10.1039/a700977a

Generation and reactivity of singlet oxygen within zeolites: Remarkable control of hydroperoxidation of alkenes

Rebecca J. Robbins, V. Ramamurthy

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

A highly selective oxidation of alkenes included within a Y zeolite is achieved by generating singlet oxygen via excitation of a monomeric dye exchanged within a zeolite; conformational control brought forth by the medium is suggested to be responsible for the observed remarkable selectivity.

Original language	English (US)
Pages (from-to)	1071-1072
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/a700977a
State	Published - Jan 1 1997
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a700977a

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title = "Generation and reactivity of singlet oxygen within zeolites: Remarkable control of hydroperoxidation of alkenes",

abstract = "A highly selective oxidation of alkenes included within a Y zeolite is achieved by generating singlet oxygen via excitation of a monomeric dye exchanged within a zeolite; conformational control brought forth by the medium is suggested to be responsible for the observed remarkable selectivity.",

author = "Robbins, {Rebecca J.} and V. Ramamurthy",

year = "1997",

month = jan,

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doi = "10.1039/a700977a",

language = "English (US)",

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journal = "Chemical Communications",

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AB - A highly selective oxidation of alkenes included within a Y zeolite is achieved by generating singlet oxygen via excitation of a monomeric dye exchanged within a zeolite; conformational control brought forth by the medium is suggested to be responsible for the observed remarkable selectivity.

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Generation and reactivity of singlet oxygen within zeolites: Remarkable control of hydroperoxidation of alkenes

Abstract

ASJC Scopus subject areas

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