Gas-Solid Reactions: Photochemical Oxidation of Thioketones in the Crystalline State

P. Arjunan; V. Ramamurthy; K. Venkatesan

doi:10.1021/jo00184a019

Gas-Solid Reactions: Photochemical Oxidation of Thioketones in the Crystalline State

P. Arjunan, V. Ramamurthy, K. Venkatesan

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20 Scopus citations

Abstract

Photochemical oxidation of 11 diaryl thioketones (1-11) was conducted in the solid state. Quite interestingly, of these only six were oxidized to the corresponding carbonyl compound whereas the rest were photostable. However, in solution all were readily oxidized. The difference in behavior between the thioketones in the solid state has been rationalized on the basis of molecular arrangement in the crystal. X-ray crystal structure analyses of four thioketones were carried out in this connection.

Original language	English (US)
Pages (from-to)	1765-1769
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	49
Issue number	10
DOIs	https://doi.org/10.1021/jo00184a019
State	Published - Jul 1984
Externally published	Yes

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Organic Chemistry

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abstract = "Photochemical oxidation of 11 diaryl thioketones (1-11) was conducted in the solid state. Quite interestingly, of these only six were oxidized to the corresponding carbonyl compound whereas the rest were photostable. However, in solution all were readily oxidized. The difference in behavior between the thioketones in the solid state has been rationalized on the basis of molecular arrangement in the crystal. X-ray crystal structure analyses of four thioketones were carried out in this connection.",

author = "P. Arjunan and V. Ramamurthy and K. Venkatesan",

year = "1984",

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AU - Venkatesan, K.

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Y1 - 1984/7

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Gas-Solid Reactions: Photochemical Oxidation of Thioketones in the Crystalline State

Abstract

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