First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes

Griet Depotter, Jean-Hubert Olivier, Mary G. Glesner, Pravas Deria, Yusong Bai, George Bullard, Amar S. Kumbhar, Michael J. Therien, Koen Clays

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

We report the first-order hyperpolarizabilities (βHRS values) of individualized, length-sorted (700 ± 50 nm long) (6,5) SWNTs and corresponding polymer-wrapped (6,5) SWNT superstructures. These SWNT-based nanohybrids feature semiconducting polymers that wrap the SWNT surface in an exclusive left-handed helical fashion. Manipulation of the polymer electronic structures in these well-defined nanoscale objects provides a new avenue to modulate the magnitude of βHRS at long wavelength (1280 nm).

Original languageEnglish (US)
Pages (from-to)12206-12209
Number of pages4
JournalChemical Communications
Volume52
Issue number82
DOIs
StatePublished - Jan 1 2016
Externally publishedYes

Fingerprint

Single-walled carbon nanotubes (SWCN)
Polymers
Semiconducting polymers
Electronic structure
Wavelength

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Depotter, G., Olivier, J-H., Glesner, M. G., Deria, P., Bai, Y., Bullard, G., ... Clays, K. (2016). First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes. Chemical Communications, 52(82), 12206-12209. https://doi.org/10.1039/c6cc06190g

First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes. / Depotter, Griet; Olivier, Jean-Hubert; Glesner, Mary G.; Deria, Pravas; Bai, Yusong; Bullard, George; Kumbhar, Amar S.; Therien, Michael J.; Clays, Koen.

In: Chemical Communications, Vol. 52, No. 82, 01.01.2016, p. 12206-12209.

Research output: Contribution to journalArticle

Depotter, G, Olivier, J-H, Glesner, MG, Deria, P, Bai, Y, Bullard, G, Kumbhar, AS, Therien, MJ & Clays, K 2016, 'First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes', Chemical Communications, vol. 52, no. 82, pp. 12206-12209. https://doi.org/10.1039/c6cc06190g
Depotter, Griet ; Olivier, Jean-Hubert ; Glesner, Mary G. ; Deria, Pravas ; Bai, Yusong ; Bullard, George ; Kumbhar, Amar S. ; Therien, Michael J. ; Clays, Koen. / First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes. In: Chemical Communications. 2016 ; Vol. 52, No. 82. pp. 12206-12209.
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