First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes

Griet Depotter; Jean Hubert Olivier; Mary G. Glesner; Pravas Deria; Yusong Bai; George Bullard; Amar S. Kumbhar; Michael J. Therien; Koen Clays

doi:10.1039/c6cc06190g

First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes

Griet Depotter, Jean Hubert Olivier, Mary G. Glesner, Pravas Deria, Yusong Bai, George Bullard, Amar S. Kumbhar, Michael J. Therien, Koen Clays

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

We report the first-order hyperpolarizabilities (β_HRS values) of individualized, length-sorted (700 ± 50 nm long) (6,5) SWNTs and corresponding polymer-wrapped (6,5) SWNT superstructures. These SWNT-based nanohybrids feature semiconducting polymers that wrap the SWNT surface in an exclusive left-handed helical fashion. Manipulation of the polymer electronic structures in these well-defined nanoscale objects provides a new avenue to modulate the magnitude of β_HRS at long wavelength (1280 nm).

Original language	English (US)
Pages (from-to)	12206-12209
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	82
DOIs	https://doi.org/10.1039/c6cc06190g
State	Published - 2016
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c6cc06190g

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First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes. / Depotter, Griet; Olivier, Jean Hubert; Glesner, Mary G.; Deria, Pravas; Bai, Yusong; Bullard, George; Kumbhar, Amar S.; Therien, Michael J.; Clays, Koen.

In: Chemical Communications, Vol. 52, No. 82, 2016, p. 12206-12209.

Research output: Contribution to journal › Article › peer-review

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title = "First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes",

abstract = "We report the first-order hyperpolarizabilities (βHRS values) of individualized, length-sorted (700 ± 50 nm long) (6,5) SWNTs and corresponding polymer-wrapped (6,5) SWNT superstructures. These SWNT-based nanohybrids feature semiconducting polymers that wrap the SWNT surface in an exclusive left-handed helical fashion. Manipulation of the polymer electronic structures in these well-defined nanoscale objects provides a new avenue to modulate the magnitude of βHRS at long wavelength (1280 nm).",

author = "Griet Depotter and Olivier, {Jean Hubert} and Glesner, {Mary G.} and Pravas Deria and Yusong Bai and George Bullard and Kumbhar, {Amar S.} and Therien, {Michael J.} and Koen Clays",

note = "Funding Information: KP thanks CSIR, India for financial support and RI thanks UGC and MKU for a non-NET fellowship. Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc06190g",

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AU - Depotter, Griet

AU - Olivier, Jean Hubert

AU - Glesner, Mary G.

AU - Deria, Pravas

AU - Bai, Yusong

AU - Bullard, George

AU - Kumbhar, Amar S.

AU - Therien, Michael J.

AU - Clays, Koen

PY - 2016

Y1 - 2016

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First-order hyperpolarizabilities of chiral, polymer-wrapped single-walled carbon nanotubes

Abstract

ASJC Scopus subject areas

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