Ferrocene derivatives included in a water-soluble cavitand

Are they electroinactive?

Dagmara Podkoscielny, Richard J. Hooley, Julius Rebek, Angel Kaifer

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

(Figure Presented) The formation in aqueous solution of kinetically stable inclusion complexes between a deep-cavity cavitand and several redox active ferrocene derivatives was demonstrated using 1H NMR spectroscopy. The electrochemical kinetics of the inclusion complexes was strongly attenuated as compared to that observed with the free guests.

Original languageEnglish
Pages (from-to)2865-2868
Number of pages4
JournalOrganic Letters
Volume10
Issue number13
DOIs
StatePublished - Dec 1 2008

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Oxidation-Reduction
Magnetic Resonance Spectroscopy
inclusions
Derivatives
Water
water
Nuclear magnetic resonance spectroscopy
aqueous solutions
nuclear magnetic resonance
cavities
Kinetics
kinetics
spectroscopy
cavitand
Proton Magnetic Resonance Spectroscopy
ferrocene

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry
  • Molecular Medicine

Cite this

Ferrocene derivatives included in a water-soluble cavitand : Are they electroinactive? / Podkoscielny, Dagmara; Hooley, Richard J.; Rebek, Julius; Kaifer, Angel.

In: Organic Letters, Vol. 10, No. 13, 01.12.2008, p. 2865-2868.

Research output: Contribution to journalArticle

Podkoscielny, Dagmara ; Hooley, Richard J. ; Rebek, Julius ; Kaifer, Angel. / Ferrocene derivatives included in a water-soluble cavitand : Are they electroinactive?. In: Organic Letters. 2008 ; Vol. 10, No. 13. pp. 2865-2868.
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