Ferrocene derivatives included in a water-soluble cavitand: Are they electroinactive?

Dagmara Podkoscielny; Richard J. Hooley; Julius Rebek; Angel E. Kaifer

doi:10.1021/ol8010375

Ferrocene derivatives included in a water-soluble cavitand: Are they electroinactive?

Dagmara Podkoscielny, Richard J. Hooley, Julius Rebek, Angel E. Kaifer

Chemistry

Research output: Contribution to journal › Article

19 Scopus citations

Abstract

(Figure Presented) The formation in aqueous solution of kinetically stable inclusion complexes between a deep-cavity cavitand and several redox active ferrocene derivatives was demonstrated using ¹H NMR spectroscopy. The electrochemical kinetics of the inclusion complexes was strongly attenuated as compared to that observed with the free guests.

Original language	English (US)
Pages (from-to)	2865-2868
Number of pages	4
Journal	Organic letters
Volume	10
Issue number	13
DOIs	https://doi.org/10.1021/ol8010375
State	Published - Dec 1 2008

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ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Cite this

Podkoscielny, D., Hooley, R. J., Rebek, J., & Kaifer, A. E. (2008). Ferrocene derivatives included in a water-soluble cavitand: Are they electroinactive? Organic letters, 10(13), 2865-2868. https://doi.org/10.1021/ol8010375

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abstract = "(Figure Presented) The formation in aqueous solution of kinetically stable inclusion complexes between a deep-cavity cavitand and several redox active ferrocene derivatives was demonstrated using 1H NMR spectroscopy. The electrochemical kinetics of the inclusion complexes was strongly attenuated as compared to that observed with the free guests.",

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AU - Kaifer, Angel E.

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N2 - (Figure Presented) The formation in aqueous solution of kinetically stable inclusion complexes between a deep-cavity cavitand and several redox active ferrocene derivatives was demonstrated using 1H NMR spectroscopy. The electrochemical kinetics of the inclusion complexes was strongly attenuated as compared to that observed with the free guests.

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Access to Document

10.1021/ol8010375