Facile dynamical intramolecular exchange of a phosphine ligand between two different metal atoms

Richard D. Adams, Burjor Captain, Wei Fu, Perry J. Pellechia

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The cluster complex PtRu5(CO)15(PMe2Ph)(μ6-C) has been shown to exhibit facile intramolecular exchange of the phosphine ligand between a platinum and ruthenium atom that is rapid on the NMR timescale at 160 °C.

Original languageEnglish
Pages (from-to)937-938
Number of pages2
JournalChemical Communications
Issue number11
StatePublished - Jun 7 2000
Externally publishedYes

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phosphine
Ruthenium
Carbon Monoxide
Platinum
Metals
Ligands
Nuclear magnetic resonance
Atoms

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Facile dynamical intramolecular exchange of a phosphine ligand between two different metal atoms. / Adams, Richard D.; Captain, Burjor; Fu, Wei; Pellechia, Perry J.

In: Chemical Communications, No. 11, 07.06.2000, p. 937-938.

Research output: Contribution to journalArticle

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