Facile dynamical intramolecular exchange of a phosphine ligand between two different metal atoms

Richard D. Adams, Burjor Captain, Wei Fu, Perry J. Pellechia

Research output: Contribution to journalArticle

27 Scopus citations

Abstract

The cluster complex PtRu5(CO)15(PMe2Ph)(μ6-C) has been shown to exhibit facile intramolecular exchange of the phosphine ligand between a platinum and ruthenium atom that is rapid on the NMR timescale at 160 °C.

Original languageEnglish (US)
Pages (from-to)937-938
Number of pages2
JournalChemical Communications
Issue number11
DOIs
StatePublished - Jun 7 2000

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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