Facile dynamical intramolecular exchange of a phosphine ligand between two different metal atoms

Richard D. Adams; Burjor Captain; Wei Fu; Perry J. Pellechia

doi:10.1039/b001080o

Facile dynamical intramolecular exchange of a phosphine ligand between two different metal atoms

Richard D. Adams, Burjor Captain, Wei Fu, Perry J. Pellechia

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

The cluster complex PtRu₅(CO)₁₅(PMe₂Ph)(μ₆-C) has been shown to exhibit facile intramolecular exchange of the phosphine ligand between a platinum and ruthenium atom that is rapid on the NMR timescale at 160 °C.

Original language	English (US)
Pages (from-to)	937-938
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/b001080o
State	Published - Jun 7 2000
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Facile dynamical intramolecular exchange of a phosphine ligand between two different metal atoms",

abstract = "The cluster complex PtRu5(CO)15(PMe2Ph)(μ6-C) has been shown to exhibit facile intramolecular exchange of the phosphine ligand between a platinum and ruthenium atom that is rapid on the NMR timescale at 160 °C.",

author = "Adams, {Richard D.} and Burjor Captain and Wei Fu and Pellechia, {Perry J.}",

year = "2000",

month = jun,

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journal = "Chemical Communications",

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AB - The cluster complex PtRu5(CO)15(PMe2Ph)(μ6-C) has been shown to exhibit facile intramolecular exchange of the phosphine ligand between a platinum and ruthenium atom that is rapid on the NMR timescale at 160 °C.

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