Extended covalent solid forms of carbon dioxide with carbon-oxygen single bonds

Nicholas Bodor, Peter Buchwald

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

Recent evidence points toward the existence at high pressures of extended covalent solid forms of carbon dioxide with carbon-oxygen single bonds. A (CO2)2n+1 polyspirotrioxane (polyspiro orthocarbonate) polymer structure proposed by us in 1992 and predicted as thermodynamically feasible and synthesizable under high pressure is consistent with the recent experimental findings.

Original languageEnglish (US)
Pages (from-to)645-649
Number of pages5
JournalChemical Physics Letters
Volume319
Issue number5-6
DOIs
StatePublished - Mar 24 2000

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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