Abstract
In this work, pulsed-field gradients are used to modulate the radiation damping field generated by the detection coil in an NMR experiment in order that spins with significantly different chemical shifts can affect one another via the radiation damping field. Experiments performed on solutions of acetone/water and acetone/ DMSO/water demonstrate that spins with chemical shift differences much greater than the effective radiation damping field strength can still be coupled by modulating the radiation damping field. Implications for applications in high-field NMR and for developing sensitive magnetization detectors are discussed.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 19985-19989 |
| Number of pages | 5 |
| Journal | Journal of Physical Chemistry B |
| Volume | 110 |
| Issue number | 40 |
| DOIs | |
| State | Published - Oct 12 2006 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Surfaces, Coatings and Films
- Materials Chemistry
Fingerprint Dive into the research topics of 'Excitation of magnetization using a modulated radiation damping field'. Together they form a unique fingerprint.
Cite this
Walls, J. D., Huang, S. Y., & Lin, Y. Y. (2006). Excitation of magnetization using a modulated radiation damping field. Journal of Physical Chemistry B, 110(40), 19985-19989. https://doi.org/10.1021/jp062319x