Abstract
Nine combinations of π-electron donors and acceptors were examined by UV-vis, fluorescence and 1H-NMR spectroscopy to identify π-stacked charge transfer complexes in macromolecular and supramolecular constructs. The high association constant of pyrene and naphthalene diimide suggests a preferentially π-stacking pair rationalized by frontier orbital congruence.
| Original language | English |
|---|---|
| Pages (from-to) | 5464-5466 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 46 |
| Issue number | 30 |
| DOIs | |
| State | Published - Aug 14 2010 |
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ASJC Scopus subject areas
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Catalysis
- Chemistry(all)
Cite this
Evidence of preferential π-stacking : A study of intermolecular and intramolecular charge transfer complexes. / Kumar, N. S Saleesh; Gujrati, Maneesh D.; Wilson, James N.
In: Chemical Communications, Vol. 46, No. 30, 14.08.2010, p. 5464-5466.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Evidence of preferential π-stacking
T2 - A study of intermolecular and intramolecular charge transfer complexes
AU - Kumar, N. S Saleesh
AU - Gujrati, Maneesh D.
AU - Wilson, James N
PY - 2010/8/14
Y1 - 2010/8/14
N2 - Nine combinations of π-electron donors and acceptors were examined by UV-vis, fluorescence and 1H-NMR spectroscopy to identify π-stacked charge transfer complexes in macromolecular and supramolecular constructs. The high association constant of pyrene and naphthalene diimide suggests a preferentially π-stacking pair rationalized by frontier orbital congruence.
AB - Nine combinations of π-electron donors and acceptors were examined by UV-vis, fluorescence and 1H-NMR spectroscopy to identify π-stacked charge transfer complexes in macromolecular and supramolecular constructs. The high association constant of pyrene and naphthalene diimide suggests a preferentially π-stacking pair rationalized by frontier orbital congruence.
UR - http://www.scopus.com/inward/record.url?scp=77954775934&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77954775934&partnerID=8YFLogxK
U2 - 10.1039/c0cc00249f
DO - 10.1039/c0cc00249f
M3 - Article
C2 - 20601985
AN - SCOPUS:77954775934
VL - 46
SP - 5464
EP - 5466
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 30
ER -