Abstract
Nine combinations of π-electron donors and acceptors were examined by UV-vis, fluorescence and 1H-NMR spectroscopy to identify π-stacked charge transfer complexes in macromolecular and supramolecular constructs. The high association constant of pyrene and naphthalene diimide suggests a preferentially π-stacking pair rationalized by frontier orbital congruence.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5464-5466 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 46 |
| Issue number | 30 |
| DOIs | |
| State | Published - Aug 14 2010 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Fingerprint Dive into the research topics of 'Evidence of preferential π-stacking: A study of intermolecular and intramolecular charge transfer complexes'. Together they form a unique fingerprint.
Cite this
Kumar, N. S. S., Gujrati, M. D., & Wilson, J. N. (2010). Evidence of preferential π-stacking: A study of intermolecular and intramolecular charge transfer complexes. Chemical Communications, 46(30), 5464-5466. https://doi.org/10.1039/c0cc00249f