Abstract
Poor agreement between 3H/3He ages and CFC-11 and CFC-12 ages suggests that CFCs may not be conservative tracers in the Everglades National Park. 3H/3He ages were used to calculate the expected concentration of CFC-11 and CFC-12 in groundwater from wells 2 to 73 m deep. The expected concentrations of CFCs were compared to the measured concentrations and plots of the % CFC-12 and CFC-11 remaining offered no evidence that significant CFC removal was occurring in the groundwater at depths ≥2 m, suggesting that CFC removal occurs at shallower depths. Except where CFC contamination was suspected, CFC-11, CFC-12 and CFC-113 concentrations in fresh surface water were nearly always below solubility equilibrium with the atmosphere. Measurements of CFC-11, CFC-12 and CFC-113 in pore water indicate a 50-90% decrease in concentration 5 cm below the groundwater-surface water (GW-SW) interface. In the same 5 cm interval CH 4 concentrations increased by 300-1000%. This suggested that CFCs were removed at the GW-SW interface, possibly by methane-producing bacteria. CFC derived recharge ages should therefore be viewed with caution when recharging water percolates through anoxic methanogenic sediments.
Original language | English (US) |
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Pages (from-to) | 94-105 |
Number of pages | 12 |
Journal | Journal of Hydrology |
Volume | 279 |
Issue number | 1-4 |
DOIs | |
State | Published - Aug 25 2003 |
Keywords
- Biodegradation
- Chlorofluorocarbons
- Groundwater
- Tracers
- Tritium
ASJC Scopus subject areas
- Water Science and Technology