Estimating the climate significance of halogen-driven ozone loss in the tropical marine troposphere

A. Saiz-Lopez, J. F. Lamarque, D. E. Kinnison, S. Tilmes, C. Ordóñez, J. J. Orlando, A. J. Conley, J. M.C. Plane, A. S. Mahajan, G. Sousa Santos, E. L. Atlas, D. R. Blake, S. P. Sander, S. Schauffler, A. M. Thompson, G. Brasseur

Research output: Contribution to journalArticle

94 Scopus citations

Abstract

We have integrated observations of tropospheric ozone, very short-lived (VSL) halocarbons and reactive iodine and bromine species from a wide variety of tropical data sources with the global CAM-Chem chemistry-climate model and offline radiative transfer calculations to compute the contribution of halogen chemistry to ozone loss and associated radiative impact in the tropical marine troposphere. The inclusion of tropospheric halogen chemistry in CAM-Chem leads to an annually averaged depletion of around 10% (∼2.5 Dobson units) of the tropical tropospheric ozone column, with largest effects in the middle to upper troposphere. This depletion contributes approximately-0.10 W m -2 to the radiative flux at the tropical tropopause. This negative flux is of similar magnitude to the ∼0.33 W m∼2 contribution of tropospheric ozone to present-day radiative balance as recently estimated from satellite observations. We find that the implementation of oceanic halogen sources and chemistry in climate models is an important component of the natural background ozone budget and we suggest that it needs to be considered when estimating both preindustrial ozone baseline levels and long term changes in tropospheric ozone.

Original languageEnglish (US)
Pages (from-to)3939-3949
Number of pages11
JournalAtmospheric Chemistry and Physics
Volume12
Issue number9
DOIs
StatePublished - May 10 2012

ASJC Scopus subject areas

  • Atmospheric Science

Fingerprint Dive into the research topics of 'Estimating the climate significance of halogen-driven ozone loss in the tropical marine troposphere'. Together they form a unique fingerprint.

  • Cite this

    Saiz-Lopez, A., Lamarque, J. F., Kinnison, D. E., Tilmes, S., Ordóñez, C., Orlando, J. J., Conley, A. J., Plane, J. M. C., Mahajan, A. S., Sousa Santos, G., Atlas, E. L., Blake, D. R., Sander, S. P., Schauffler, S., Thompson, A. M., & Brasseur, G. (2012). Estimating the climate significance of halogen-driven ozone loss in the tropical marine troposphere. Atmospheric Chemistry and Physics, 12(9), 3939-3949. https://doi.org/10.5194/acp-12-3939-2012