Equilibrium constants for the formation of Cu(I) halide complexes

Virender K. Sharma, Frank J. Millero

Research output: Contribution to journalArticle

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Abstract

The stoichiometric equilibrium constants, K 3 *, for the formation of CuX 3 2- from CuX 2 - +X- where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45°C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, β0, β1 and Cφ, for the interaction of Na+ with CuX 2 - and CuX 3 2- are briefly discussed.

Original languageEnglish (US)
Pages (from-to)375-390
Number of pages16
JournalJournal of Solution Chemistry
Volume19
Issue number4
DOIs
StatePublished - Apr 1 1990

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Keywords

  • CuBr
  • CuCl
  • Equilibrium constants
  • Pitzer equations
  • complexes
  • spectral data

ASJC Scopus subject areas

  • Biophysics
  • Biochemistry
  • Molecular Biology
  • Physical and Theoretical Chemistry

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