Abstract
The stoichiometric equilibrium constants, K 3 *, for the formation of CuX 3 2- from CuX 2 - +X- where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45°C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, β0, β1 and Cφ, for the interaction of Na+ with CuX 2 - and CuX 3 2- are briefly discussed.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 375-390 |
| Number of pages | 16 |
| Journal | Journal of Solution Chemistry |
| Volume | 19 |
| Issue number | 4 |
| DOIs | |
| State | Published - Apr 1990 |
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Keywords
- complexes
- CuBr
- CuCl
- Equilibrium constants
- Pitzer equations
- spectral data
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Molecular Biology
- Biophysics
- Biochemistry
Cite this
Equilibrium constants for the formation of Cu(I) halide complexes. / Sharma, Virender K.; Millero, Frank J.
In: Journal of Solution Chemistry, Vol. 19, No. 4, 04.1990, p. 375-390.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Equilibrium constants for the formation of Cu(I) halide complexes
AU - Sharma, Virender K.
AU - Millero, Frank J
PY - 1990/4
Y1 - 1990/4
N2 - The stoichiometric equilibrium constants, K 3 *, for the formation of CuX 3 2- from CuX 2 - +X- where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45°C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, β0, β1 and Cφ, for the interaction of Na+ with CuX 2 - and CuX 3 2- are briefly discussed.
AB - The stoichiometric equilibrium constants, K 3 *, for the formation of CuX 3 2- from CuX 2 - +X- where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45°C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, β0, β1 and Cφ, for the interaction of Na+ with CuX 2 - and CuX 3 2- are briefly discussed.
KW - complexes
KW - CuBr
KW - CuCl
KW - Equilibrium constants
KW - Pitzer equations
KW - spectral data
UR - http://www.scopus.com/inward/record.url?scp=51249177354&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=51249177354&partnerID=8YFLogxK
U2 - 10.1007/BF00648142
DO - 10.1007/BF00648142
M3 - Article
VL - 19
SP - 375
EP - 390
JO - Journal of Solution Chemistry
JF - Journal of Solution Chemistry
SN - 0095-9782
IS - 4
ER -