Abstract
(equation presented) Obtaining a high enantiomeric excess during a photoreaction within a zeolite is hampered by the statistical distribution of reactant and chiral inductor molecules within the cages of a zeolite. By restricting the photoreactions to only those cages that contain both the reactant and a chiral inductor, one should be able to avoid reactions that yield racemic products. This approach is illustrated with the photoreduction of an arylalkyl ketone by a chiral inductor with an amino group.
| Original language | English |
|---|---|
| Pages (from-to) | 937-940 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 2 |
| Issue number | 7 |
| State | Published - Apr 6 2000 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Molecular Medicine
Cite this
Enantioselective photoreduction of arylalkyl ketones via restricting the reaction to chirally modified zeolite cages. / Shailaja, J.; Ponchot, Keith J.; Ramamurthy, Vaidhyanathan.
In: Organic Letters, Vol. 2, No. 7, 06.04.2000, p. 937-940.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Enantioselective photoreduction of arylalkyl ketones via restricting the reaction to chirally modified zeolite cages
AU - Shailaja, J.
AU - Ponchot, Keith J.
AU - Ramamurthy, Vaidhyanathan
PY - 2000/4/6
Y1 - 2000/4/6
N2 - (equation presented) Obtaining a high enantiomeric excess during a photoreaction within a zeolite is hampered by the statistical distribution of reactant and chiral inductor molecules within the cages of a zeolite. By restricting the photoreactions to only those cages that contain both the reactant and a chiral inductor, one should be able to avoid reactions that yield racemic products. This approach is illustrated with the photoreduction of an arylalkyl ketone by a chiral inductor with an amino group.
AB - (equation presented) Obtaining a high enantiomeric excess during a photoreaction within a zeolite is hampered by the statistical distribution of reactant and chiral inductor molecules within the cages of a zeolite. By restricting the photoreactions to only those cages that contain both the reactant and a chiral inductor, one should be able to avoid reactions that yield racemic products. This approach is illustrated with the photoreduction of an arylalkyl ketone by a chiral inductor with an amino group.
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UR - http://www.scopus.com/inward/citedby.url?scp=0001266633&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0001266633
VL - 2
SP - 937
EP - 940
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 7
ER -