Electrochemically driven formation of a molecular capsule around the ferrocenium ion

Ivy E. Philip, Angel E. Kaifer

Research output: Contribution to journalArticlepeer-review

75 Scopus citations

Abstract

Electrochemical experiments were used to show that the oxidation of ferrocene triggers the self-assembly of six molecules of the resocin[4]arene 2 to form a molecular capsule around the oxidized, ferrocenium (+1) form. The nature of the supporting electrolyte anion is crucial for this process of electrochemically driven self-assembly. 1H NMR spectroscopic data obtained with cobaltocenium, a diamagnetic analogue of the paramagnetic ferrocenium ion, verify its encapsulation by six molecules of 2. The encapsulation of cobaltocenium was also observed in voltammetric experiments. Encapsulation of ferrocenium (or cobaltocenium) inside the large 26 capsule led to a dramatic slowing of its usually fast, one-electron electrochemical reduction to ferrocene (or cobaltocene).

Original languageEnglish (US)
Pages (from-to)12678-12679
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number43
DOIs
StatePublished - Oct 30 2002

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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