Effect of pressure on sulfate ion association in sea water

Frank J. Millero

doi:10.1016/0016-7037(71)90027-5

Effect of pressure on sulfate ion association in sea water

Frank J. Millero

Ocean Sciences

Research output: Contribution to journal › Article

22 Scopus citations

Abstract

The effect of pressure on the association of Mg²⁺, Ca²⁺ and Na⁺ with SO₄^2- in seawater is estimated from partial molal volume data. The results indicate that the concentration of the ion-pair MgSO₄° in seawater decreases with increasing pressure as expected, rather than increasing as estimated by Kester and Pytkowicz (1970).

Original language	English (US)
Pages (from-to)	1089-1098
Number of pages	10
Journal	Geochimica et Cosmochimica Acta
Volume	35
Issue number	11
DOIs	https://doi.org/10.1016/0016-7037(71)90027-5
State	Published - Nov 1971

ASJC Scopus subject areas

Geochemistry and Petrology

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10.1016/0016-7037(71)90027-5

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Millero, F. J. (1971). Effect of pressure on sulfate ion association in sea water. Geochimica et Cosmochimica Acta, 35(11), 1089-1098. https://doi.org/10.1016/0016-7037(71)90027-5

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abstract = "The effect of pressure on the association of Mg2+, Ca2+ and Na+ with SO42- in seawater is estimated from partial molal volume data. The results indicate that the concentration of the ion-pair MgSO4° in seawater decreases with increasing pressure as expected, rather than increasing as estimated by Kester and Pytkowicz (1970).",

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AB - The effect of pressure on the association of Mg2+, Ca2+ and Na+ with SO42- in seawater is estimated from partial molal volume data. The results indicate that the concentration of the ion-pair MgSO4° in seawater decreases with increasing pressure as expected, rather than increasing as estimated by Kester and Pytkowicz (1970).

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