Effect of pressure on sulfate ion association in sea water

Frank J. Millero

doi:10.1016/0016-7037(71)90027-5

Effect of pressure on sulfate ion association in sea water

Frank J. Millero

Ocean Sciences

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The effect of pressure on the association of Mg²⁺, Ca²⁺ and Na⁺ with SO₄^2- in seawater is estimated from partial molal volume data. The results indicate that the concentration of the ion-pair MgSO₄° in seawater decreases with increasing pressure as expected, rather than increasing as estimated by Kester and Pytkowicz (1970).

Original language	English (US)
Pages (from-to)	1089-1098
Number of pages	10
Journal	Geochimica et Cosmochimica Acta
Volume	35
Issue number	11
DOIs	https://doi.org/10.1016/0016-7037(71)90027-5
State	Published - Nov 1971

ASJC Scopus subject areas

Geochemistry and Petrology

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10.1016/0016-7037(71)90027-5

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title = "Effect of pressure on sulfate ion association in sea water",

abstract = "The effect of pressure on the association of Mg2+, Ca2+ and Na+ with SO42- in seawater is estimated from partial molal volume data. The results indicate that the concentration of the ion-pair MgSO4° in seawater decreases with increasing pressure as expected, rather than increasing as estimated by Kester and Pytkowicz (1970).",

author = "Millero, {Frank J.}",

note = "Funding Information: t Contribution Number 1390 from the Rosenstiel School of Marine and Atmospheric Science. The author wishes to acknowledge the support of the National Science Foundation (GA 17386) end the Office of Naval Research (NONR 4008-02) for this work. 1 1089",

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AU - Millero, Frank J.

N1 - Funding Information: t Contribution Number 1390 from the Rosenstiel School of Marine and Atmospheric Science. The author wishes to acknowledge the support of the National Science Foundation (GA 17386) end the Office of Naval Research (NONR 4008-02) for this work. 1 1089

PY - 1971/11

Y1 - 1971/11

N2 - The effect of pressure on the association of Mg2+, Ca2+ and Na+ with SO42- in seawater is estimated from partial molal volume data. The results indicate that the concentration of the ion-pair MgSO4° in seawater decreases with increasing pressure as expected, rather than increasing as estimated by Kester and Pytkowicz (1970).

AB - The effect of pressure on the association of Mg2+, Ca2+ and Na+ with SO42- in seawater is estimated from partial molal volume data. The results indicate that the concentration of the ion-pair MgSO4° in seawater decreases with increasing pressure as expected, rather than increasing as estimated by Kester and Pytkowicz (1970).

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IS - 11

ER -

Effect of pressure on sulfate ion association in sea water

Abstract

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