Dynamics of sodium cation complexation by carbon- and nitrogen-pivot lariat ethers

Angel Kaifer, H. Dupont Durst, Luis Echegoyen, Dennis M. Dishong, Rose Ann Schultz, George W. Gokel

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

13C NMR relaxation time (T1) measurements for carbon-pivot and nitrogen-pivot lariat ethers indicate that the latter are more dynamic complexers and that in some cases, the side-arm oxygens appear to participate more strongly in the overall binding than do the ring oxygens.

Original languageEnglish
Pages (from-to)3195-3197
Number of pages3
JournalJournal of Organic Chemistry
Volume47
Issue number16
StatePublished - Dec 1 1982
Externally publishedYes

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Ethers
Complexation
Cations
Nitrogen
Carbon
Sodium
Oxygen
Time measurement
Relaxation time
Nuclear magnetic resonance

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Kaifer, A., Durst, H. D., Echegoyen, L., Dishong, D. M., Schultz, R. A., & Gokel, G. W. (1982). Dynamics of sodium cation complexation by carbon- and nitrogen-pivot lariat ethers. Journal of Organic Chemistry, 47(16), 3195-3197.

Dynamics of sodium cation complexation by carbon- and nitrogen-pivot lariat ethers. / Kaifer, Angel; Durst, H. Dupont; Echegoyen, Luis; Dishong, Dennis M.; Schultz, Rose Ann; Gokel, George W.

In: Journal of Organic Chemistry, Vol. 47, No. 16, 01.12.1982, p. 3195-3197.

Research output: Contribution to journalArticle

Kaifer, A, Durst, HD, Echegoyen, L, Dishong, DM, Schultz, RA & Gokel, GW 1982, 'Dynamics of sodium cation complexation by carbon- and nitrogen-pivot lariat ethers', Journal of Organic Chemistry, vol. 47, no. 16, pp. 3195-3197.
Kaifer A, Durst HD, Echegoyen L, Dishong DM, Schultz RA, Gokel GW. Dynamics of sodium cation complexation by carbon- and nitrogen-pivot lariat ethers. Journal of Organic Chemistry. 1982 Dec 1;47(16):3195-3197.
Kaifer, Angel ; Durst, H. Dupont ; Echegoyen, Luis ; Dishong, Dennis M. ; Schultz, Rose Ann ; Gokel, George W. / Dynamics of sodium cation complexation by carbon- and nitrogen-pivot lariat ethers. In: Journal of Organic Chemistry. 1982 ; Vol. 47, No. 16. pp. 3195-3197.
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