Dynamics of Sodium Cation Complexation by Carbon- and Nitrogen-Pivot Lariat Ethers

Angel Kaifer, H. Dupont Durst, Luis Echegoyen, Dennis M. Dishong, Rose Ann Schultz, George W. Gokel

Research output: Contribution to journalLetter

27 Scopus citations

Abstract

13C NMR relaxation time (T1) measurements for carbon-pivot and nitrogen-pivot lariat ethers indicate that the latter are more dynamic complexers and that in some cases, the side-arm oxygens appear to participate more strongly in the overall binding than do the ring oxygens.

Original languageEnglish (US)
Pages (from-to)3195-3197
Number of pages3
JournalJournal of Organic Chemistry
Volume47
Issue number16
DOIs
StatePublished - Jan 1 1982
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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    Kaifer, A., Durst, H. D., Echegoyen, L., Dishong, D. M., Schultz, R. A., & Gokel, G. W. (1982). Dynamics of Sodium Cation Complexation by Carbon- and Nitrogen-Pivot Lariat Ethers. Journal of Organic Chemistry, 47(16), 3195-3197. https://doi.org/10.1021/jo00137a042