Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)

Michael P. Edwards; Carl Hoff; Basil Curnutte; John S. Eck; Keith F. Purcell

Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)

Michael P. Edwards, Carl Hoff, Basil Curnutte, John S. Eck, Keith F. Purcell

Research output: Contribution to journal › Article

Abstract

Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)₂(NCBH₃)₂ reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

Original language	English
Pages (from-to)	2613-2619
Number of pages	7
Journal	Inorganic Chemistry
Volume	23
Issue number	17
State	Published - Dec 1 1984
Externally published	Yes

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Inorganic Chemistry

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Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II). / Edwards, Michael P.; Hoff, Carl; Curnutte, Basil; Eck, John S.; Purcell, Keith F.

In: Inorganic Chemistry, Vol. 23, No. 17, 01.12.1984, p. 2613-2619.

Research output: Contribution to journal › Article

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abstract = "Variable-temperature M{\"o}ssbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. M{\"o}ssbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.",

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AU - Edwards, Michael P.

AU - Hoff, Carl

AU - Curnutte, Basil

AU - Eck, John S.

AU - Purcell, Keith F.

PY - 1984/12/1

Y1 - 1984/12/1

N2 - Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

AB - Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

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JO - Inorganic Chemistry

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ER -

Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)

Abstract

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