Abstract
Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.
Original language | English (US) |
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Pages (from-to) | 2613-2619 |
Number of pages | 7 |
Journal | Inorganic Chemistry |
Volume | 23 |
Issue number | 17 |
DOIs | |
State | Published - Aug 1984 |
Externally published | Yes |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry