Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)

Michael P. Edwards; D. Carl Hoff; Basil Curnutte; John S. Eck; Keith F. Purcell

doi:10.1021/ic00185a015

Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)

Michael P. Edwards, D. Carl Hoff, Basil Curnutte, John S. Eck, Keith F. Purcell

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)₂(NCBH₃)₂ reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

Original language	English (US)
Pages (from-to)	2613-2619
Number of pages	7
Journal	Inorganic Chemistry
Volume	23
Issue number	17
DOIs	https://doi.org/10.1021/ic00185a015
State	Published - Aug 1984
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00185a015

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title = "Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)",

abstract = "Variable-temperature M{\"o}ssbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. M{\"o}ssbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.",

author = "Edwards, {Michael P.} and {Carl Hoff}, D. and Basil Curnutte and Eck, {John S.} and Purcell, {Keith F.}",

year = "1984",

month = aug,

doi = "10.1021/ic00185a015",

language = "English (US)",

volume = "23",

pages = "2613--2619",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)

AU - Edwards, Michael P.

AU - Carl Hoff, D.

AU - Curnutte, Basil

AU - Eck, John S.

AU - Purcell, Keith F.

PY - 1984/8

Y1 - 1984/8

N2 - Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

AB - Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

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U2 - 10.1021/ic00185a015

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JF - Inorganic Chemistry

SN - 0020-1669

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ER -

Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)

Abstract

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