Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)

Michael P. Edwards; D. Carl Hoff; Basil Curnutte; John S. Eck; Keith F. Purcell

doi:10.1021/ic00185a015

Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)

Michael P. Edwards, D. Carl Hoff, Basil Curnutte, John S. Eck, Keith F. Purcell

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)₂(NCBH₃)₂ reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

Original language	English (US)
Pages (from-to)	2613-2619
Number of pages	7
Journal	Inorganic Chemistry
Volume	23
Issue number	17
DOIs	https://doi.org/10.1021/ic00185a015
State	Published - Aug 1984
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)",

abstract = "Variable-temperature M{\"o}ssbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. M{\"o}ssbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.",

author = "Edwards, {Michael P.} and {Carl Hoff}, D. and Basil Curnutte and Eck, {John S.} and Purcell, {Keith F.}",

year = "1984",

month = aug,

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issn = "0020-1669",

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AU - Eck, John S.

AU - Purcell, Keith F.

PY - 1984/8

Y1 - 1984/8

N2 - Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

AB - Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

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