Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)

Michael P. Edwards, Carl Hoff, Basil Curnutte, John S. Eck, Keith F. Purcell

Research output: Contribution to journal › Article

16 Citations (Scopus)

Abstract

Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

Original languageEnglish
Pages (from-to)2613-2619
Number of pages7
JournalInorganic Chemistry
Volume23
Issue number17
StatePublished - Dec 1 1984
Externally publishedYes

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Phenanthrolines
Iron
occurrences
iron
Magnetic susceptibility
Infrared radiation
magnetic permeability
Temperature
room temperature
temperature

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Edwards, M. P., Hoff, C., Curnutte, B., Eck, J. S., & Purcell, K. F. (1984). Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II). Inorganic Chemistry, 23(17), 2613-2619.

Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II). / Edwards, Michael P.; Hoff, Carl; Curnutte, Basil; Eck, John S.; Purcell, Keith F.

In: Inorganic Chemistry, Vol. 23, No. 17, 01.12.1984, p. 2613-2619.

Research output: Contribution to journal › Article

Edwards, MP, Hoff, C, Curnutte, B, Eck, JS & Purcell, KF 1984, 'Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)', Inorganic Chemistry, vol. 23, no. 17, pp. 2613-2619.
Edwards MP, Hoff C, Curnutte B, Eck JS, Purcell KF. Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II). Inorganic Chemistry. 1984 Dec 1;23(17):2613-2619.
Edwards, Michael P. ; Hoff, Carl ; Curnutte, Basil ; Eck, John S. ; Purcell, Keith F. / Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II). In: Inorganic Chemistry. 1984 ; Vol. 23, No. 17. pp. 2613-2619.
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