Dynamic Intersystem Crossing in Solid Bis(Phenanthroline)bis(Cyanotrihydroborato)Iron(II)

Michael P. Edwards, D. Carl Hoff, Basil Curnutte, John S. Eck, Keith F. Purcell

Research output: Contribution to journalArticle

16 Scopus citations

Abstract

Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

Original languageEnglish (US)
Pages (from-to)2613-2619
Number of pages7
JournalInorganic Chemistry
Volume23
Issue number17
DOIs
StatePublished - Aug 1984
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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