Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II)

Michael P. Edwards, Carl Hoff, Basil Curnutte, John S. Eck, Keith F. Purcell

Research output: Contribution to journalArticle

16 Scopus citations

Abstract

Variable-temperature Mössbauer, magnetic susceptibility, and infrared studies of Fe(phen)2(NCBH3)2 reveal the occurrence of a reversible, gradual singlet/quintet intersystem crossing above room temperature. Mössbauer spectra of the complex in the transition region are interpreted as showing the occurrence of a novel (for Fe(II)), fast singlet/quintet interconversion.

Original languageEnglish
Pages (from-to)2613-2619
Number of pages7
JournalInorganic Chemistry
Volume23
Issue number17
StatePublished - Dec 1 1984
Externally publishedYes

    Fingerprint

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Dynamic intersystem crossing in solid bis(phenanthroline)bis(cyanotrihydroborato)iron(II). / Edwards, Michael P.; Hoff, Carl; Curnutte, Basil; Eck, John S.; Purcell, Keith F.

In: Inorganic Chemistry, Vol. 23, No. 17, 01.12.1984, p. 2613-2619.

Research output: Contribution to journalArticle