Dynamic characteristics and mitigations of hydrogen starvations in proton exchange membrane fuel cells during start-ups

Fei Jia, Liejin Guo, Hongtan Liu

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Hydrogen starvation during a start-up process in proton exchange membrane (PEM) fuel cells could result in drastic local current density variations, reverse cell voltage and irreversible cell damages. In this work, variations of local current densities and temperatures are measured in situ under both potentiostatic and galvanostatic modes. Experimental results show that when the cell starts up under potentiostatic mode with hydrogen starvation, current density undershoots occur in the downstream; while under the galvanostatic mode, local current density in the downstream almost drops to zero, but the current density near the outlet remains almost constant. The phenomenon of near constant current density near the outlet leads to a novel approach to alleviate hydrogen starvations - a hydrogen reservoir is added at the anode outlet. Experimental results show that the exit hydrogen reservoir can significantly reduce the zero current region and alleviate hydrogen starvations. A non-dimensional current-density variation coefficient is proposed to measure the magnitude of local current density changes during starvations. Experimental results show that the exit hydrogen reservoir can significantly reduce the current-density variations coefficient over the entire flow channel, indicating that adding an exit reservoir is an effective approach in mitigating hydrogen starvations.

Original languageEnglish
Pages (from-to)12835-12841
Number of pages7
JournalInternational Journal of Hydrogen Energy
Volume39
Issue number24
DOIs
StatePublished - Aug 13 2014

Fingerprint

Proton exchange membrane fuel cells (PEMFC)
dynamic characteristics
fuel cells
Current density
current density
membranes
Hydrogen
protons
hydrogen
outlets
channel flow
Channel flow
coefficients
cells
Anodes
anodes
Cells
damage
Electric potential
electric potential

Keywords

  • Dynamic characteristic
  • Hydrogen starvation
  • Proton exchange membrane fuel cell
  • Start-up

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Dynamic characteristics and mitigations of hydrogen starvations in proton exchange membrane fuel cells during start-ups. / Jia, Fei; Guo, Liejin; Liu, Hongtan.

In: International Journal of Hydrogen Energy, Vol. 39, No. 24, 13.08.2014, p. 12835-12841.

Research output: Contribution to journalArticle

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