Abstract
Reduction potentials for anthracene, pyrene, perylene, and nitrobenzene, their perdeuterated forms, and 15N-enriched nitrobenzene were measured by using voltammetric techniques. The results indicated that the perdeuterated forms have lower solution electron affinities than the isotopically unmodified counterparts since the former exhibit slightly more negative reduction potentials. However, 15N enrichment was not observed to cause any significant effects under our experimental conditions.
| Original language | English |
|---|---|
| Pages (from-to) | 7682-7683 |
| Number of pages | 2 |
| Journal | Journal of Physical Chemistry |
| Volume | 94 |
| Issue number | 19 |
| State | Published - Dec 1 1990 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
Cite this
Does isotopic substitution affect the reduction potential of aromatic molecules? / Goodnow, Timothy T.; Kaifer, Angel.
In: Journal of Physical Chemistry, Vol. 94, No. 19, 01.12.1990, p. 7682-7683.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Does isotopic substitution affect the reduction potential of aromatic molecules?
AU - Goodnow, Timothy T.
AU - Kaifer, Angel
PY - 1990/12/1
Y1 - 1990/12/1
N2 - Reduction potentials for anthracene, pyrene, perylene, and nitrobenzene, their perdeuterated forms, and 15N-enriched nitrobenzene were measured by using voltammetric techniques. The results indicated that the perdeuterated forms have lower solution electron affinities than the isotopically unmodified counterparts since the former exhibit slightly more negative reduction potentials. However, 15N enrichment was not observed to cause any significant effects under our experimental conditions.
AB - Reduction potentials for anthracene, pyrene, perylene, and nitrobenzene, their perdeuterated forms, and 15N-enriched nitrobenzene were measured by using voltammetric techniques. The results indicated that the perdeuterated forms have lower solution electron affinities than the isotopically unmodified counterparts since the former exhibit slightly more negative reduction potentials. However, 15N enrichment was not observed to cause any significant effects under our experimental conditions.
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UR - http://www.scopus.com/inward/citedby.url?scp=0011570978&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0011570978
VL - 94
SP - 7682
EP - 7683
JO - Journal of Physical Chemistry
JF - Journal of Physical Chemistry
SN - 0022-3654
IS - 19
ER -