Disulfido iron-manganese carbonyl cluster complexes: Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)73-S2)2

Richard D. Adams, Erin M. Boswell, Burjor Captain, Shaobin Miao, Chad Beddie, Charles Edwin Webster, Michael B. Hall, Naresh S. Dalal, Narpinder Kaur, David Zipse

Research output: Contribution to journalArticle

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Abstract

Two new compounds CpFeMn2(CO)73-S2)2 (2) and Cp3Fe3Mn(CO)43-S 2)23-S) (3) were obtained by the treatment of [CpFeMn(CO)53-S2)]2 (1) with CO at room temperature in the presence of room light.

Original languageEnglish (US)
Pages (from-to)2732-2738
Number of pages7
JournalJournal of Organometallic Chemistry
Volume693
Issue number16
DOIs
StatePublished - Aug 1 2008
Externally publishedYes

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Keywords

  • Disulfido
  • Iron
  • Manganese
  • Molecular orbitals
  • Radical

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Materials Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Biochemistry

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