Abstract
A pulsed laser photolysis - pulsed laser induced fluorescence technique has been employed to carry out direct, real time studies of OH reactions with DMS and DMS-d//6 in N//2, air and O//2 buffer gases. Both temperature and pressure dependencies have been investigated. It is found that the observed rate constant depends on the O//2 concentration. Results are consistent with a mechanism which includes an abstraction route, a reversible addition route, and an adduct plus O//2 reaction which competes with adduct decomposition under atmospheric conditions.
| Original language | English (US) |
|---|---|
| Title of host publication | American Chemical Society, Division of Petroleum Chemistry, Preprints |
| Editors | W.E. Haines |
| Publisher | ACS |
| Pages | 568-572 |
| Number of pages | 5 |
| Volume | 31 |
| Edition | 2 |
| State | Published - Apr 1986 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Fuel Technology
Cite this
DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS. / Hynes, Anthony J; Wine, P. H.
American Chemical Society, Division of Petroleum Chemistry, Preprints. ed. / W.E. Haines. Vol. 31 2. ed. ACS, 1986. p. 568-572.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS.
AU - Hynes, Anthony J
AU - Wine, P. H.
PY - 1986/4
Y1 - 1986/4
N2 - A pulsed laser photolysis - pulsed laser induced fluorescence technique has been employed to carry out direct, real time studies of OH reactions with DMS and DMS-d//6 in N//2, air and O//2 buffer gases. Both temperature and pressure dependencies have been investigated. It is found that the observed rate constant depends on the O//2 concentration. Results are consistent with a mechanism which includes an abstraction route, a reversible addition route, and an adduct plus O//2 reaction which competes with adduct decomposition under atmospheric conditions.
AB - A pulsed laser photolysis - pulsed laser induced fluorescence technique has been employed to carry out direct, real time studies of OH reactions with DMS and DMS-d//6 in N//2, air and O//2 buffer gases. Both temperature and pressure dependencies have been investigated. It is found that the observed rate constant depends on the O//2 concentration. Results are consistent with a mechanism which includes an abstraction route, a reversible addition route, and an adduct plus O//2 reaction which competes with adduct decomposition under atmospheric conditions.
UR - http://www.scopus.com/inward/record.url?scp=0022700862&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0022700862&partnerID=8YFLogxK
M3 - Conference contribution
VL - 31
SP - 568
EP - 572
BT - American Chemical Society, Division of Petroleum Chemistry, Preprints
A2 - Haines, W.E.
PB - ACS
ER -