Abstract
A pulsed laser photolysis - pulsed laser induced fluorescence technique has been employed to carry out direct, real time studies of OH reactions with DMS and DMS-d//6 in N//2, air and O//2 buffer gases. Both temperature and pressure dependencies have been investigated. It is found that the observed rate constant depends on the O//2 concentration. Results are consistent with a mechanism which includes an abstraction route, a reversible addition route, and an adduct plus O//2 reaction which competes with adduct decomposition under atmospheric conditions.
Original language | English (US) |
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Pages (from-to) | 568-572 |
Number of pages | 5 |
Journal | American Chemical Society, Division of Petroleum Chemistry, Preprints |
Volume | 31 |
Issue number | 2 |
State | Published - Apr 1 1986 |
Externally published | Yes |
ASJC Scopus subject areas
- Fuel Technology