DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS.

Anthony J Hynes, P. H. Wine

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A pulsed laser photolysis - pulsed laser induced fluorescence technique has been employed to carry out direct, real time studies of OH reactions with DMS and DMS-d//6 in N//2, air and O//2 buffer gases. Both temperature and pressure dependencies have been investigated. It is found that the observed rate constant depends on the O//2 concentration. Results are consistent with a mechanism which includes an abstraction route, a reversible addition route, and an adduct plus O//2 reaction which competes with adduct decomposition under atmospheric conditions.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Division of Petroleum Chemistry, Preprints
EditorsW.E. Haines
PublisherACS
Pages568-572
Number of pages5
Volume31
Edition2
StatePublished - Apr 1986
Externally publishedYes

Fingerprint

Pulsed lasers
Time and motion study
Kinetics
Photolysis
Rate constants
Fluorescence
Decomposition
Air
Gases
Temperature

ASJC Scopus subject areas

  • Fuel Technology

Cite this

Hynes, A. J., & Wine, P. H. (1986). DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS. In W. E. Haines (Ed.), American Chemical Society, Division of Petroleum Chemistry, Preprints (2 ed., Vol. 31, pp. 568-572). ACS.

DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS. / Hynes, Anthony J; Wine, P. H.

American Chemical Society, Division of Petroleum Chemistry, Preprints. ed. / W.E. Haines. Vol. 31 2. ed. ACS, 1986. p. 568-572.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Hynes, AJ & Wine, PH 1986, DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS. in WE Haines (ed.), American Chemical Society, Division of Petroleum Chemistry, Preprints. 2 edn, vol. 31, ACS, pp. 568-572.
Hynes AJ, Wine PH. DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS. In Haines WE, editor, American Chemical Society, Division of Petroleum Chemistry, Preprints. 2 ed. Vol. 31. ACS. 1986. p. 568-572
Hynes, Anthony J ; Wine, P. H. / DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS. American Chemical Society, Division of Petroleum Chemistry, Preprints. editor / W.E. Haines. Vol. 31 2. ed. ACS, 1986. pp. 568-572
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