A pulsed laser photolysis - pulsed laser induced fluorescence technique has been employed to carry out direct, real time studies of OH reactions with DMS and DMS-d//6 in N//2, air and O//2 buffer gases. Both temperature and pressure dependencies have been investigated. It is found that the observed rate constant depends on the O//2 concentration. Results are consistent with a mechanism which includes an abstraction route, a reversible addition route, and an adduct plus O//2 reaction which competes with adduct decomposition under atmospheric conditions.
|Original language||English (US)|
|Number of pages||5|
|Journal||American Chemical Society, Division of Petroleum Chemistry, Preprints|
|State||Published - Apr 1 1986|
ASJC Scopus subject areas
- Fuel Technology