DIRECT KINETIC AND MECHANISTIC STUDY OF THE OH plus DIMETHYLSULFIDE REACTION UNDER ATMOSPHERIC CONDITIONS.

A. J. Hynes, P. H. Wine

Research output: Contribution to journalConference article

Abstract

A pulsed laser photolysis - pulsed laser induced fluorescence technique has been employed to carry out direct, real time studies of OH reactions with DMS and DMS-d//6 in N//2, air and O//2 buffer gases. Both temperature and pressure dependencies have been investigated. It is found that the observed rate constant depends on the O//2 concentration. Results are consistent with a mechanism which includes an abstraction route, a reversible addition route, and an adduct plus O//2 reaction which competes with adduct decomposition under atmospheric conditions.

Original languageEnglish (US)
Pages (from-to)568-572
Number of pages5
JournalAmerican Chemical Society, Division of Petroleum Chemistry, Preprints
Volume31
Issue number2
StatePublished - Apr 1 1986
Externally publishedYes

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ASJC Scopus subject areas

  • Fuel Technology

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