Detection of isomeric microscopic host-guest complexes. a time-evolving cucurbit[7]uril complex

Mohammad Hossein Tootoonchi, Song Yi, Angel E. Kaifer

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

The formation of inclusion complexes between the cucurbit[7]uril host and a cationic guest containing ferrocenylmethyl and adamantyl residues connected to an ammonium nitrogen initially leads to an ∼1:1 mixture of two isomeric microscopic complexes, which evolves as a function of time toward the thermodynamically stable mixture, dominated by the adamantyl-included complex.

Original languageEnglish (US)
Pages (from-to)10804-10809
Number of pages6
JournalJournal of the American Chemical Society
Volume135
Issue number29
DOIs
StatePublished - Jul 24 2013

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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