Cucurbituril and cyclodextrin complexes of dendrimers

Wei Wang, Angel E. Kaifer

Research output: Chapter in Book/Report/Conference proceedingChapter

30 Scopus citations

Abstract

This chapter reviews the growing body of data on the binding interactions between dendrimers and two types of well-established molecular hosts: cyclodextrins and cucurbit[n]urils. Dendrimers are highly branched macromolecules to which functional groups can be attached in spatially defined locations. The attachment of guest functional groups to dendrimers allows the investigation of their binding interactions with freely diffusing hosts/receptors. The effect of dendrimer size on the thermodynamics of these host-guest reactions varies widely depending on factors described here. In optimum cases, it is possible to use these binding interactions to exert redox control on dendrimer self-assembly and even control the size of the resulting assemblies.

Original languageEnglish (US)
Title of host publicationAdvances in Polymer Science
EditorsGerhard Wenz
Pages205-235
Number of pages31
Edition1
DOIs
StatePublished - Dec 1 2009

Publication series

NameAdvances in Polymer Science
Number1
Volume222
ISSN (Print)0065-3195

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Keywords

  • Cobaltocenium
  • Cucurbit[n]urils
  • Cyclodextrins
  • Dendrimers
  • Ferrocene
  • Host-guest complexation
  • Inclusion complexes
  • Viologens

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Chemical Engineering(all)

Cite this

Wang, W., & Kaifer, A. E. (2009). Cucurbituril and cyclodextrin complexes of dendrimers. In G. Wenz (Ed.), Advances in Polymer Science (1 ed., pp. 205-235). (Advances in Polymer Science; Vol. 222, No. 1). https://doi.org/10.1007/12-2008-1