Cucurbit[8]uril-mediated redox-controlled self-assembly of viologen-containing dendrimers

Kwangyul Moon; Jodi Grindstaff; David Sobransingh; Angel E. Kaifer

doi:10.1002/anie.200460179

Cucurbit[8]uril-mediated redox-controlled self-assembly of viologen-containing dendrimers

Kwangyul Moon, Jodi Grindstaff, David Sobransingh, Angel E. Kaifer

Chemistry

Research output: Contribution to journal › Article › peer-review

153 Scopus citations

Abstract

The dimerization of dendrimers that contain a single 4,4′- bipyridinium (viologen) unit, upon one-electron reduction, is strongly enhanced by the presence of the host cucurbit[8]uril. This behavior is attributed to the formation of a stable inclusion complex between the host and two π-stacked viologen radical-cation guests-the one-electron-reduced form of viologen (see scheme).

Original language	English (US)
Pages (from-to)	5496-5499
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	41
DOIs	https://doi.org/10.1002/anie.200460179
State	Published - Oct 18 2004

Keywords

Dendrimers
Dimerization
Host-guest systems
Redox chemistry
Self-assembly

ASJC Scopus subject areas

Chemistry(all)

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10.1002/anie.200460179

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abstract = "The dimerization of dendrimers that contain a single 4,4′- bipyridinium (viologen) unit, upon one-electron reduction, is strongly enhanced by the presence of the host cucurbit[8]uril. This behavior is attributed to the formation of a stable inclusion complex between the host and two π-stacked viologen radical-cation guests-the one-electron-reduced form of viologen (see scheme).",

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AU - Grindstaff, Jodi

AU - Sobransingh, David

AU - Kaifer, Angel E.

PY - 2004/10/18

Y1 - 2004/10/18

N2 - The dimerization of dendrimers that contain a single 4,4′- bipyridinium (viologen) unit, upon one-electron reduction, is strongly enhanced by the presence of the host cucurbit[8]uril. This behavior is attributed to the formation of a stable inclusion complex between the host and two π-stacked viologen radical-cation guests-the one-electron-reduced form of viologen (see scheme).

AB - The dimerization of dendrimers that contain a single 4,4′- bipyridinium (viologen) unit, upon one-electron reduction, is strongly enhanced by the presence of the host cucurbit[8]uril. This behavior is attributed to the formation of a stable inclusion complex between the host and two π-stacked viologen radical-cation guests-the one-electron-reduced form of viologen (see scheme).

KW - Dendrimers

KW - Dimerization

KW - Host-guest systems

KW - Redox chemistry

KW - Self-assembly

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ER -

Cucurbit[8]uril-mediated redox-controlled self-assembly of viologen-containing dendrimers

Abstract

Keywords

ASJC Scopus subject areas

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