Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre

Roger Harrison, Atta M. Arif, Gary Wulfsberg, Russell Lang, Telvin Ju, Gabor Kiss, Carl Hoff, Thomas G. Richmond

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Abstract

A new series of chelate stabilized aryl halide coordination complexes of molybdenum are prepared by a novel oxidative addition strategy; quantitative equilibrium measurements suggest that the structure of the chelate ring, rather than the identity of the halide (X = Cl, Br, I), controls the strength of aryl halide binding in these complexes.

Original languageEnglish
Pages (from-to)1374-1376
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number18
DOIs
StatePublished - Dec 1 1992

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ASJC Scopus subject areas

  • Molecular Medicine

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