Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre

Roger Harrison, Atta M. Arif, Gary Wulfsberg, Russell Lang, Telvin Ju, Gabor Kiss, Carl Hoff, Thomas G. Richmond

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A new series of chelate stabilized aryl halide coordination complexes of molybdenum are prepared by a novel oxidative addition strategy; quantitative equilibrium measurements suggest that the structure of the chelate ring, rather than the identity of the halide (X = Cl, Br, I), controls the strength of aryl halide binding in these complexes.

Original languageEnglish
Pages (from-to)1374-1376
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number18
DOIs
StatePublished - Dec 1 1992

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Molybdenum
Coordination Complexes

ASJC Scopus subject areas

  • Molecular Medicine

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Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre. / Harrison, Roger; Arif, Atta M.; Wulfsberg, Gary; Lang, Russell; Ju, Telvin; Kiss, Gabor; Hoff, Carl; Richmond, Thomas G.

In: Journal of the Chemical Society, Chemical Communications, No. 18, 01.12.1992, p. 1374-1376.

Research output: Contribution to journalArticle

Harrison, Roger ; Arif, Atta M. ; Wulfsberg, Gary ; Lang, Russell ; Ju, Telvin ; Kiss, Gabor ; Hoff, Carl ; Richmond, Thomas G. / Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre. In: Journal of the Chemical Society, Chemical Communications. 1992 ; No. 18. pp. 1374-1376.
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