Controlling photochemistry with distinct hydrophobic nanoenvironments

Lakshmi S. Kaanumalle; Corinne L.D. Gibb; Bruce C. Gibb; V. Ramamurthy

doi:10.1021/ja0450197

Controlling photochemistry with distinct hydrophobic nanoenvironments

Lakshmi S. Kaanumalle, Corinne L.D. Gibb, Bruce C. Gibb, V. Ramamurthy

Research output: Contribution to journal › Article › peer-review

136 Scopus citations

Abstract

A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm × 2 nm cavity.

Original language	English (US)
Pages (from-to)	14366-14367
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	44
DOIs	https://doi.org/10.1021/ja0450197
State	Published - Nov 10 2004
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0450197

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title = "Controlling photochemistry with distinct hydrophobic nanoenvironments",

abstract = "A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm × 2 nm cavity.",

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AU - Gibb, Bruce C.

AU - Ramamurthy, V.

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Y1 - 2004/11/10

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AB - A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm × 2 nm cavity.

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Controlling photochemistry with distinct hydrophobic nanoenvironments

Abstract

ASJC Scopus subject areas

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