Controlling photochemical reactions via confinement: Zeolites

V. Ramamurthy

doi:10.1016/S1389-5567(00)00010-1

Controlling photochemical reactions via confinement: Zeolites

V. Ramamurthy

Research output: Contribution to journal › Review article › peer-review

65 Scopus citations

Abstract

Zeolites, aluminosilicates, with well-defined internal architecture containing cavities, channels or cages, can accommodate a large number of organic guest molecules. Internal structure of zeolites is studded with cations, the counter-ions of the anionic framework. The internal constrained structure and the cations serve as handles for chemists to control the behaviour of guest molecules included within zeolites. Photochemical reactions carried out in zeolite are highlighted in this review.

Original language	English (US)
Pages (from-to)	145-166
Number of pages	22
Journal	Journal of Photochemistry and Photobiology C: Photochemistry Reviews
Volume	1
Issue number	2
DOIs	https://doi.org/10.1016/S1389-5567(00)00010-1
State	Published - Dec 29 2000
Externally published	Yes

Keywords

Asymmetric induction
Heavy atom effect
Light atom effect
Supramolecular chemistry
Zeolites

ASJC Scopus subject areas

Bioengineering
Physical and Theoretical Chemistry

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10.1016/S1389-5567(00)00010-1

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AB - Zeolites, aluminosilicates, with well-defined internal architecture containing cavities, channels or cages, can accommodate a large number of organic guest molecules. Internal structure of zeolites is studded with cations, the counter-ions of the anionic framework. The internal constrained structure and the cations serve as handles for chemists to control the behaviour of guest molecules included within zeolites. Photochemical reactions carried out in zeolite are highlighted in this review.

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KW - Light atom effect

KW - Supramolecular chemistry

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