CO 2 solubility in seawater at high pressures

J. Safarov; S. Berndt; F. M. Millero; R. Feistel; A. Henitz; E. Hassel

doi:10.1002/cite.201250510

CO ₂ solubility in seawater at high pressures

J. Safarov, S. Berndt, F. M. Millero, R. Feistel, A. Henitz, E. Hassel

Ocean Sciences

Research output: Contribution to specialist publication › Article

Abstract

Some of the important atmospheric gases are added to seawater from the atmosphere through the constant movement of the sea surface by wind and waves. The amount of CO ₂ dissolved in saturated seawater is unusually high. Oceans have a large storage capacity for (anthropogenic) CO ₂. Direct discharge and sequestration of captured CO ₂ in the deep ocean has been considered as a means to mitigate global warming. New CO ₂ solubility measurements in seawater at high pressures, various temperatures, and salinities were presented. Using the fugacity of CO ₂ at given values of temperature and the equilibrium pressure of full system, the fugacity coefficient of CO ₂ and Henry's law for CO ₂ solubility were calculated. The CO ₂ solubilities in seawater in dependence of temperature, pressure, and salinity were analyzed.

Original language	English (US)
Pages	1415
Number of pages	1
Volume	84
No	8
Specialist publication	Chemie-Ingenieur-Technik
DOIs	https://doi.org/10.1002/cite.201250510
State	Published - Aug 2012

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Industrial and Manufacturing Engineering

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10.1002/cite.201250510

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abstract = "Some of the important atmospheric gases are added to seawater from the atmosphere through the constant movement of the sea surface by wind and waves. The amount of CO 2 dissolved in saturated seawater is unusually high. Oceans have a large storage capacity for (anthropogenic) CO 2. Direct discharge and sequestration of captured CO 2 in the deep ocean has been considered as a means to mitigate global warming. New CO 2 solubility measurements in seawater at high pressures, various temperatures, and salinities were presented. Using the fugacity of CO 2 at given values of temperature and the equilibrium pressure of full system, the fugacity coefficient of CO 2 and Henry's law for CO 2 solubility were calculated. The CO 2 solubilities in seawater in dependence of temperature, pressure, and salinity were analyzed.",

author = "J. Safarov and S. Berndt and Millero, {F. M.} and R. Feistel and A. Henitz and E. Hassel",

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AU - Safarov, J.

AU - Berndt, S.

AU - Millero, F. M.

AU - Feistel, R.

AU - Henitz, A.

AU - Hassel, E.

PY - 2012/8

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AB - Some of the important atmospheric gases are added to seawater from the atmosphere through the constant movement of the sea surface by wind and waves. The amount of CO 2 dissolved in saturated seawater is unusually high. Oceans have a large storage capacity for (anthropogenic) CO 2. Direct discharge and sequestration of captured CO 2 in the deep ocean has been considered as a means to mitigate global warming. New CO 2 solubility measurements in seawater at high pressures, various temperatures, and salinities were presented. Using the fugacity of CO 2 at given values of temperature and the equilibrium pressure of full system, the fugacity coefficient of CO 2 and Henry's law for CO 2 solubility were calculated. The CO 2 solubilities in seawater in dependence of temperature, pressure, and salinity were analyzed.

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