CH3SH photolysis at 248 nm. Hydrogen atom yield and rate constant for the H + CH3SH reaction

P. H. Wine; J. M. Nicovich; A. J. Hynes; J. R. Wells

doi:10.1021/j100408a041

CH₃SH photolysis at 248 nm. Hydrogen atom yield and rate constant for the H + CH₃SH reaction

P. H. Wine, J. M. Nicovich, A. J. Hynes, J. R. Wells

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Hydrogen atoms have been detected by time-resolved resonance fluorescence spectroscopy following 248-nm pulsed-laser photolysis of CH₃SH. The primary photolysis yield of H atoms has been determined to be 1.08 ± 0.24 by comparing fluorescence signals observed following CH₃SH photolysis with those observed following photolysis of O₃/H₂ mixtures. The kinetics of the H + CH₃SH reaction have been investigated. Over the temperature range 249-405 K the rate constant is given by the Arrhenius expression k = (3.45 ± 0.13) × 10^-11 exp[-(845 ± 12)/T] cm³ molecule^-1 s^-1.

Original language	English (US)
Pages (from-to)	4033-4037
Number of pages	5
Journal	Journal of physical chemistry
Volume	90
Issue number	17
DOIs	https://doi.org/10.1021/j100408a041
State	Published - 1986
Externally published	Yes

ASJC Scopus subject areas

Engineering(all)
Physical and Theoretical Chemistry

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title = "CH3SH photolysis at 248 nm. Hydrogen atom yield and rate constant for the H + CH3SH reaction",

abstract = "Hydrogen atoms have been detected by time-resolved resonance fluorescence spectroscopy following 248-nm pulsed-laser photolysis of CH3SH. The primary photolysis yield of H atoms has been determined to be 1.08 ± 0.24 by comparing fluorescence signals observed following CH3SH photolysis with those observed following photolysis of O3/H2 mixtures. The kinetics of the H + CH3SH reaction have been investigated. Over the temperature range 249-405 K the rate constant is given by the Arrhenius expression k = (3.45 ± 0.13) × 10-11 exp[-(845 ± 12)/T] cm3 molecule-1 s-1.",

author = "Wine, {P. H.} and Nicovich, {J. M.} and Hynes, {A. J.} and Wells, {J. R.}",

year = "1986",

doi = "10.1021/j100408a041",

language = "English (US)",

volume = "90",

pages = "4033--4037",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - CH3SH photolysis at 248 nm. Hydrogen atom yield and rate constant for the H + CH3SH reaction

AU - Wine, P. H.

AU - Nicovich, J. M.

AU - Hynes, A. J.

AU - Wells, J. R.

PY - 1986

Y1 - 1986

N2 - Hydrogen atoms have been detected by time-resolved resonance fluorescence spectroscopy following 248-nm pulsed-laser photolysis of CH3SH. The primary photolysis yield of H atoms has been determined to be 1.08 ± 0.24 by comparing fluorescence signals observed following CH3SH photolysis with those observed following photolysis of O3/H2 mixtures. The kinetics of the H + CH3SH reaction have been investigated. Over the temperature range 249-405 K the rate constant is given by the Arrhenius expression k = (3.45 ± 0.13) × 10-11 exp[-(845 ± 12)/T] cm3 molecule-1 s-1.

AB - Hydrogen atoms have been detected by time-resolved resonance fluorescence spectroscopy following 248-nm pulsed-laser photolysis of CH3SH. The primary photolysis yield of H atoms has been determined to be 1.08 ± 0.24 by comparing fluorescence signals observed following CH3SH photolysis with those observed following photolysis of O3/H2 mixtures. The kinetics of the H + CH3SH reaction have been investigated. Over the temperature range 249-405 K the rate constant is given by the Arrhenius expression k = (3.45 ± 0.13) × 10-11 exp[-(845 ± 12)/T] cm3 molecule-1 s-1.

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