Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane

Deborah A. Gustowski; Vincent J. Gatto; Angel Kaifer; Luis Echegoyen; Robert E. Godt; George W. Gokel

doi:10.1039/C39840000923

Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane

Deborah A. Gustowski, Vincent J. Gatto, Angel Kaifer, Luis Echegoyen, Robert E. Godt, George W. Gokel

Research output: Contribution to journal › Article

24 Scopus citations

Abstract

Azobenzenes are shown for the first time to exhibit substantial Li ⁺ and Na⁺ cation effects on their electrochemical behaviour, and although K⁺ does not interact with Ar-N=N-Ar, or its reduced form, a strong interaction is observed when K⁺ is bound as a cryptate complex.

Original language	English (US)
Pages (from-to)	923-925
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39840000923
State	Published - Jan 1 1984
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39840000923

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Gustowski, D. A., Gatto, V. J., Kaifer, A., Echegoyen, L., Godt, R. E., & Gokel, G. W. (1984). Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane. Journal of the Chemical Society, Chemical Communications, (14), 923-925. https://doi.org/10.1039/C39840000923

Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane. / Gustowski, Deborah A.; Gatto, Vincent J.; Kaifer, Angel; Echegoyen, Luis; Godt, Robert E.; Gokel, George W.

In: Journal of the Chemical Society, Chemical Communications, No. 14, 01.01.1984, p. 923-925.

Research output: Contribution to journal › Article

Gustowski, DA, Gatto, VJ, Kaifer, A, Echegoyen, L, Godt, RE & Gokel, GW 1984, 'Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane', Journal of the Chemical Society, Chemical Communications, no. 14, pp. 923-925. https://doi.org/10.1039/C39840000923

Gustowski DA, Gatto VJ, Kaifer A, Echegoyen L, Godt RE, Gokel GW. Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane. Journal of the Chemical Society, Chemical Communications. 1984 Jan 1;(14):923-925. https://doi.org/10.1039/C39840000923

Gustowski, Deborah A. ; Gatto, Vincent J. ; Kaifer, Angel ; Echegoyen, Luis ; Godt, Robert E. ; Gokel, George W. / Cation effects on the cyclic voltammograms of azotoluene and the potassium cation selectivity of the electrochemically reduced azo-cryptand 7,16-azobis(1,3-phenylenemethylene)-1,4,10,13-tetraoxa-7,16-diazaoctadecane. In: Journal of the Chemical Society, Chemical Communications. 1984 ; No. 14. pp. 923-925.

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