Abstract
The complexation of trimethyl(ferrocenylmethyl)ammonium hexafluorophosphate 1·(BF6), heptyldimethyl(ferrocenylmethyl)ammonium bromide 2·(Br) and ferrocenylmethanol 3 by a sulfonated calix[6]arene host was investigated in aqueous media using electrochemical and 1H NMR spectroscopic techniques; the binding interactions between the calixarene host and the surveyed guests are similar to those operating in the complexation of organic compounds by cyclodextrin or cyclophane hosts in aqueous media.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1017-1019 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 12 |
| DOIs | |
| State | Published - Dec 1 1993 |
ASJC Scopus subject areas
- Molecular Medicine
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Zhang, L., MacÍas, A., Lu, T., Gordon, J. I., Gokel, G. W., & Kaifer, A. E. (1993). Calixarenes as hosts in aqueous media: Inclusion complexation of ferrocene derivatives by a water-soluble calix[6]arene. Journal of the Chemical Society, Chemical Communications, (12), 1017-1019. https://doi.org/10.1039/C39930001017