Calixarenes as hosts in aqueous media: Inclusion complexation of ferrocene derivatives by a water-soluble calix[6]arene

Litao Zhang; Alba MacÍas; Tianbao Lu; Jeffrey I. Gordon; George W. Gokel; Angel E. Kaifer

doi:10.1039/C39930001017

Calixarenes as hosts in aqueous media: Inclusion complexation of ferrocene derivatives by a water-soluble calix[6]arene

Litao Zhang, Alba MacÍas, Tianbao Lu, Jeffrey I. Gordon, George W. Gokel, Angel E. Kaifer

Chemistry

Research output: Contribution to journal › Article

62 Scopus citations

Abstract

The complexation of trimethyl(ferrocenylmethyl)ammonium hexafluorophosphate 1·(BF₆), heptyldimethyl(ferrocenylmethyl)ammonium bromide 2·(Br) and ferrocenylmethanol 3 by a sulfonated calix[6]arene host was investigated in aqueous media using electrochemical and ¹H NMR spectroscopic techniques; the binding interactions between the calixarene host and the surveyed guests are similar to those operating in the complexation of organic compounds by cyclodextrin or cyclophane hosts in aqueous media.

Original language	English (US)
Pages (from-to)	1017-1019
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39930001017
State	Published - Dec 1 1993

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ASJC Scopus subject areas

Molecular Medicine

Cite this

Zhang, L., MacÍas, A., Lu, T., Gordon, J. I., Gokel, G. W., & Kaifer, A. E. (1993). Calixarenes as hosts in aqueous media: Inclusion complexation of ferrocene derivatives by a water-soluble calix[6]arene. Journal of the Chemical Society, Chemical Communications, (12), 1017-1019. https://doi.org/10.1039/C39930001017

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10.1039/C39930001017