Bisaminoferrocenyl triazine derivatives: Effects of the third substituent on the extent of interaction between the metal centers

Wei Wang; Dongmei Xu; Daniel Gesua; Burjor Captain; Angel E. Kaifer

doi:10.1007/s10008-013-2162-8

Bisaminoferrocenyl triazine derivatives: Effects of the third substituent on the extent of interaction between the metal centers

Wei Wang, Dongmei Xu, Daniel Gesua, Burjor Captain, Angel E. Kaifer

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We prepared a new series of bisaminoferrocenyl triazine derivatives and investigated their anodic voltammetric behavior. The electronic nature of the third substituent on the triazine nucleus, that is, its electronic donor/acceptor character determines the level of interactions between the two ferrocenyl centers as measured by the separation between their two oxidation half-wave potentials.

Original language	English (US)
Pages (from-to)	3063-3066
Number of pages	4
Journal	Journal of Solid State Electrochemistry
Volume	17
Issue number	12
DOIs	https://doi.org/10.1007/s10008-013-2162-8
State	Published - Dec 2013

Keywords

Electronic effects
Electronic interactions
Ferrocene
Voltammetry

ASJC Scopus subject areas

Electrochemistry
Electrical and Electronic Engineering
Condensed Matter Physics
Materials Science(all)

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10.1007/s10008-013-2162-8

Cite this

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title = "Bisaminoferrocenyl triazine derivatives: Effects of the third substituent on the extent of interaction between the metal centers",

abstract = "We prepared a new series of bisaminoferrocenyl triazine derivatives and investigated their anodic voltammetric behavior. The electronic nature of the third substituent on the triazine nucleus, that is, its electronic donor/acceptor character determines the level of interactions between the two ferrocenyl centers as measured by the separation between their two oxidation half-wave potentials.",

keywords = "Electronic effects, Electronic interactions, Ferrocene, Voltammetry",

author = "Wei Wang and Dongmei Xu and Daniel Gesua and Burjor Captain and Kaifer, {Angel E.}",

note = "Funding Information: The authors are grateful to the NSF (to AEK, CHE-0600795 and CHE-0848637) and the Jiangsu Government Scholarship for Oversea Studies, Natural Science Foundation of Jiangsu Province Education Committee (to DMX, no. 06KJB150103) for the generous support of this work. WW acknowledges support from the University of Miami in the form of a Maytag Graduate Fellowship. DG was sponsored by the Honors and Executive Internship Program of Miami-Dade County Public Schools. ",

year = "2013",

month = dec,

doi = "10.1007/s10008-013-2162-8",

language = "English (US)",

volume = "17",

pages = "3063--3066",

journal = "Journal of Solid State Electrochemistry",

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TY - JOUR

T1 - Bisaminoferrocenyl triazine derivatives

T2 - Effects of the third substituent on the extent of interaction between the metal centers

AU - Wang, Wei

AU - Xu, Dongmei

AU - Gesua, Daniel

AU - Captain, Burjor

AU - Kaifer, Angel E.

N1 - Funding Information: The authors are grateful to the NSF (to AEK, CHE-0600795 and CHE-0848637) and the Jiangsu Government Scholarship for Oversea Studies, Natural Science Foundation of Jiangsu Province Education Committee (to DMX, no. 06KJB150103) for the generous support of this work. WW acknowledges support from the University of Miami in the form of a Maytag Graduate Fellowship. DG was sponsored by the Honors and Executive Internship Program of Miami-Dade County Public Schools.

PY - 2013/12

Y1 - 2013/12

N2 - We prepared a new series of bisaminoferrocenyl triazine derivatives and investigated their anodic voltammetric behavior. The electronic nature of the third substituent on the triazine nucleus, that is, its electronic donor/acceptor character determines the level of interactions between the two ferrocenyl centers as measured by the separation between their two oxidation half-wave potentials.

AB - We prepared a new series of bisaminoferrocenyl triazine derivatives and investigated their anodic voltammetric behavior. The electronic nature of the third substituent on the triazine nucleus, that is, its electronic donor/acceptor character determines the level of interactions between the two ferrocenyl centers as measured by the separation between their two oxidation half-wave potentials.

KW - Electronic effects

KW - Electronic interactions

KW - Ferrocene

KW - Voltammetry

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VL - 17

SP - 3063

EP - 3066

JO - Journal of Solid State Electrochemistry

JF - Journal of Solid State Electrochemistry

SN - 1432-8488

IS - 12

ER -

Bisaminoferrocenyl triazine derivatives: Effects of the third substituent on the extent of interaction between the metal centers

Abstract

Keywords

ASJC Scopus subject areas

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