Binding selectivity of cucurbit[7]uril: Bis(pyridinium)-1,4-xylylene versus 4,4′-bipyridinium guest sites

Vladimir Sindelar, Kwangyul Moon, Angel E. Kaifer

Research output: Contribution to journalArticle

100 Scopus citations

Abstract

The binding interactions between the host cucurbit[7]uril (CB7) and a series of linear guests containing bis(pyridinium)-1,4-xylylene and/or 4,4′-bipyridinium residues were investigated by 1H NMR spectroscopy. CB7 was found to exhibit considerable binding selectivity for bis-(pyridinium)-1,4-xylylene over 4,4′-bipyridinium sites. New pseudo-rotaxane and rotaxane compounds were synthesized utilizing the host-guest interactions between CB7 and the surveyed guests.

Original languageEnglish (US)
Pages (from-to)2665-2668
Number of pages4
JournalOrganic letters
Volume6
Issue number16
DOIs
StatePublished - Aug 5 2004

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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