Aqueous-phase synthesis of PAA in PVDF membrane pores for nanoparticle synthesis and dichlorobiphenyl degradation

V. Smuleac, Leonidas G Bachas, D. Bhattacharyya

Research output: Contribution to journalArticle

73 Citations (Scopus)

Abstract

This paper deals with bimetallic (Fe/Pd) nanoparticle synthesis inside the membrane pores and application for catalytic dechlorination of toxic organic compounds form aqueous streams. Membranes have been used as platforms for nanoparticle synthesis in order to reduce the agglomeration, encountered in solution phase synthesis which leads to a dramatic loss of reactivity. The membrane support, polyvinylidene fluoride (PVDF) was modified by in situ polymerization of acrylic acid in aqueous phase. Subsequent steps included ion exchange with Fe2+, reduction to Fe0 with sodium borohydride and Pd deposition. Various techniques, such as STEM, EDX, FTIR and permeability measurements, were used for membrane characterization and showed that bimetallic (Fe/Pd) nanoparticles with an average size of 20-30 nm have been incorporated inside of the PAA-coated membrane pores. The Fe/Pd-modified membranes showed a high reactivity toward a model compound, 2,2′-dichlorobiphenyl and a strong dependence of degradation on Pd (hydrogenation catalyst) content. The use of convective flow substantially reduces the degradation time: 43% conversion of dichlorobiphenyl to biphenyl can be achieved in less than 40 s residence time. Another important aspect is the ability to regenerate and reuse the Fe/Pd bimetallic systems by washing with a solution of sodium borohydride, because the iron becomes inactivated (corroded) as the dechlorination reaction proceeds.

Original languageEnglish (US)
Pages (from-to)310-317
Number of pages8
JournalJournal of Membrane Science
Volume346
Issue number2
DOIs
StatePublished - Jan 15 2010
Externally publishedYes

Fingerprint

vinylidene
Nanoparticles
fluorides
degradation
membranes
Membranes
porosity
Degradation
nanoparticles
synthesis
Dechlorination
borohydrides
reactivity
Sodium
sodium
Scanning Transmission Electron Microscopy
Hydrogenation
convective flow
reuse
Poisons

Keywords

  • Catalysis
  • Dechlorination
  • Fe/Pd bimetallic nanoparticles
  • Microfiltration membrane
  • PCB

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Science(all)
  • Biochemistry
  • Filtration and Separation

Cite this

Aqueous-phase synthesis of PAA in PVDF membrane pores for nanoparticle synthesis and dichlorobiphenyl degradation. / Smuleac, V.; Bachas, Leonidas G; Bhattacharyya, D.

In: Journal of Membrane Science, Vol. 346, No. 2, 15.01.2010, p. 310-317.

Research output: Contribution to journalArticle

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